{"id":273,"date":"2014-10-10T10:20:07","date_gmt":"2014-10-09T23:20:07","guid":{"rendered":"http:\/\/new.radio-active.net.au\/web3\/?page_id=273"},"modified":"2014-10-10T10:20:23","modified_gmt":"2014-10-09T23:20:23","slug":"chemical-history-of-a-candle","status":"publish","type":"page","link":"http:\/\/www.radio-active.net.au\/web3\/Personal\/History\/Candle","title":{"rendered":"Chemical History of a Candle"},"content":{"rendered":"<p><H1>Modern History Sourcebook: <BR>Michael Faraday<br \/>\n<SMALL><SMALL>(1791-1867)<\/SMALL><\/SMALL>: <BR>The Chemical History of A Candle,<br \/>\n1860<\/H1><\/p>\n<p><HR><br \/>\n<BLOCKQUOTE><br \/>\n  <P><STRONG>Introductory Note<\/STRONG><\/P><br \/>\n  <P><EM>Michael Faraday was the son of a blacksmith, and was born at Newington<br \/>\n  Butts, near London, September 22, 1791. He began life as an errand boy to a<br \/>\n  bookbinder and stationer, to whom he was later bound apprentice. After eight<br \/>\n  years in this business, he was engaged by Sir Humphry Davy as his laboratory<br \/>\n  assistant at the Royal Institution, and in 1813-15 he traveled extensively on<br \/>\n  the Continent with his master, and saw some of the most famous scientists of<br \/>\n  Europe. Shortly after his return to the Royal Institution, he began to make<br \/>\n  contributions of his own to science, his first paper appearing in 1816. He<br \/>\n  became director of the laboratory in 1825, and professor of chemistry in 1833;<br \/>\n  rising rapidly, through the number and importance of his discoveries, to a<br \/>\n  most distinguished position. But he was working at too great pressure, and in<br \/>\n  1841 his health gave way, so that for some three years he could not work at<br \/>\n  all. He recovered, however, and made some of his most important discoveries<br \/>\n  after this interruption; and was offered, but declined, the presidency of both<br \/>\n  the Royal Society and the Royal Institution. He died August 25, 1867.<\/EM><\/P><br \/>\n  <P><EM>It was characteristic of Faraday&#8217;s devotion to the enlargement of the<br \/>\n  bounds of human knowledge that on his discovery of magneto-electricity he<br \/>\n  abandoned the commercial work by which he had added to his small salary, in<br \/>\n  order to reserve all his energies for research. This financial loss was in<br \/>\n  part made up later by a pension of 300 pounds a year from the British<br \/>\n  Government.<\/EM><\/P><br \/>\n  <P><EM>Faraday&#8217;s parents were members of the obscure religious denomination of<br \/>\n  the Sandemanians, and Faraday himself, shortly after his marriage, at the age<br \/>\n  of thirty, joined the same sect, to which he adhered till his death. Religion<br \/>\n  and science he kept strictly apart, believing that the data of science were of<br \/>\n  an entirely different nature from the direct communications between God and<br \/>\n  the soul on which his religious faith was based.<\/EM><\/P><br \/>\n  <P><EM>The discoveries made by Faraday were so numerous, and often demand so<br \/>\n  detailed a knowledge of chemistry and physics before they can be understood,<br \/>\n  that it is impossible to attempt to describe or even enumerate them here.<br \/>\n  Among the most important are the discovery of magneto-electric induction, of<br \/>\n  the law of electro-chemical decomposition, of the magnetization of light, and<br \/>\n  of diamagnetism. Round each of these are grouped numbers of derivative but<br \/>\n  still highly important additions to scientific knowledge, and together they<br \/>\n  form so vast an achievement as to lead his successor, Tyndall, to say, &#8220;Taking<br \/>\n  him for all and all, I think it will be conceded that Michael Faraday was the<br \/>\n  greatest experimental philosopher the world has ever seen; and I will add the<br \/>\n  opinion, that the progress of future research will tend, not to dim or to<br \/>\n  diminish, but to enhance and glorify the labours of this mighty<br \/>\n  investigator.&#8221;<\/EM><\/P><\/p>\n<p>  <P><EM>In spite of the highly technical nature of his work in research,<br \/>\n  Faraday was remarkably gifted as an expounder of science to popular audiences;<br \/>\n  and his lectures at the Royal Institution, especially those to younger<br \/>\n  audiences, were justly famous. The following example is a classic in the<br \/>\n  department of clear and fascinating scientific exposition.<\/EM><br \/>\n  <UL><br \/>\n    <LI>Lecture I: <A href=\"#Lecture I\">A<br \/>\n    Candle: The Flame &#8211; Its Sources &#8211; Structure Mobility &#8211; Brightness<\/A><br \/>\n    <LI>Lecture II: <A\n    href=\"#Lecture II\">Brightness<br \/>\n    of The Flame &#8211; Air Necessary For Combustion &#8211; Production of Water<\/A><br \/>\n    <LI>Lecture III: <A\n    href=\"#Lecture III\">Products:<br \/>\n    Water From The Combustion &#8211; Nature of Water &#8211; A Compound &#8211; Hydrogen<\/A><\/p>\n<p>    <LI>Lecture IV:<A\n    href=\"#Lecture IV\"><br \/>\n    Hydrogen in The Candle &#8211; Burns Into Water &#8211; The Other Part of Water &#8211;<br \/>\n    Oxygen<\/A><br \/>\n    <LI>Lecture V: <A\n    href=\"#Lecture V\">Oxygen<br \/>\n    Present in The Air &#8211; Nature of The Atmosphere &#8211; Carbonic Acid<\/A><br \/>\n    <LI>Lecture VI: <A\n    href=\"#Lecture VI\">Carbon<br \/>\n    or Charcoal &#8211; Coal Gas &#8211; Respiration and Its Analogy to A Candle<\/A><br \/>\n<\/LI><\/UL><br \/>\n  <HR><\/p>\n<p>  <P><br \/>\n<STRONG><br \/>\n<a name=\"Lecture I\">Lecture I<\/a>: A Candle: The Flame &#8211;<br \/>\n  Its Sources &#8211; Structure Mobility &#8211; Brightness<br \/>\n<\/STRONG><br \/>\n<\/P><br \/>\n  <P>I purpose, in return for the honor you do us by coming to see what are our<br \/>\n  proceedings here, to bring before you, in the course of these lectures, the<br \/>\n  Chemical History of a Candle. I have taken this subject on a former occasion,<br \/>\n  and, were it left to my own will, I should prefer to repeat it almost every<br \/>\n  year, so abundant is the interest that attaches itself to the subject, so<br \/>\n  wonderful are the varieties of outlet which it offers into the various<br \/>\n  departments of philosophy. There is not a law under which any part of this<br \/>\n  universe is governed which does not come into play and is touched upon in<br \/>\n  these phenomena. There is no better, there is no more open door by which you<br \/>\n  can enter into the study of natural philosophy than by considering the<br \/>\n  physical phenomena of a candle. I trust, therefore, I shall not disappoint you<br \/>\n  in choosing this for my subject rather than any newer topic, which could not<br \/>\n  be better, were it even so good.<\/P><br \/>\n  <P>And, before proceeding, let me say this also: that, though our subject be<br \/>\n  so great, and our intention that of treating it honestly, seriously, and<br \/>\n  philosophically, yet I mean to pass away from all those who are seniors among<br \/>\n  us. I claim the privilege of speaking to juveniles as a juvenile myself. I<br \/>\n  have done so on former occasions, and, if you please, I shall do so again.<br \/>\n  And, though I stand here with the knowledge of having the words I utter given<br \/>\n  to the world, yet that shall not deter me from speaking in the same familiar<br \/>\n  way to those whom I esteem nearest to me on this occasion.<\/P><br \/>\n  <P>And now, my boys and girls, I must first tell you of what candles are made.<br \/>\n  Some are great curiosities. I have here some bits of timber, branches of trees<br \/>\n  particularly famous for their burning. And here you see a piece of that very<br \/>\n  curious substance, taken out of some of the bogs in Ireland, called<br \/>\n  candle-wood; a hard, strong, excellent wood, evidently fitted for good work as<br \/>\n  a register of force, and yet, withal, burning so well that where it is found<br \/>\n  they make splinters of it, and torches, since it burns like a candle, and<br \/>\n  gives a very good light indeed. And in this wood we have one of the most<br \/>\n  beautiful illustrations of the general nature of a candle that I can possibly<br \/>\n  give. The fuel provided, the means of bringing that fuel to the place of<br \/>\n  chemical action, the regular and gradual supply of air to that place of action<br \/>\n  &#8211; heat and light &#8211; all produced by a little piece of wood of this kind,<br \/>\n  forming, in fact, a natural candle.<\/P><br \/>\n  <P>But we must speak of candles as they are in commerce. Here are a couple of<br \/>\n  candles commonly called dips. They are made of lengths of cotton cut off, hung<br \/>\n  up by a loop, dipped into melted tallow, taken out again and cooled, then<br \/>\n  redipped, until there is an accumulation of tallow round the cotton. In order<br \/>\n  that you may have an idea of the various characters of these candles, you see<br \/>\n  these which I hold in my hand &#8211; they are very small and very curious. They<br \/>\n  are, or were, the candles used by the miners in coal mines. In olden times the<br \/>\n  miner had to find his own candles, and it was supposed that a small candle<br \/>\n  would not so soon set fire to the fire-damp in the coal mines as a large one;<br \/>\n  and for that reason, as well as for economy&#8217;s sake, he had candles made of<br \/>\n  this sort &#8211; 20, 30, 40, or 60 to the pound. They have been replaced since then<br \/>\n  by the steel-mill, and then by the Davy lamp, and other safety lamps of<br \/>\n  various kinds. I have here a candle that was taken out of the Royal George<br \/>\n  <SUP>1<\/SUP>, it is said, by Colonel Pasley. It has been sunk in the sea for<br \/>\n  many years, subject to the action of salt water. It shows you how well candles<br \/>\n  may be preserved; for, though it is cracked about and broken a great deal, yet<br \/>\n  when lighted it goes on burning regularly, and the tallow resumes its natural<br \/>\n  condition as soon as it is fused.<\/P><\/p>\n<p>  <BLOCKQUOTE><br \/>\n    <P>[Footnote 1: The Royal George sunk at Spithead on the 29th of August,<br \/>\n    1782. Colonel Pasley commenced operations for the removal of the wreck by<br \/>\n    the explosion of gunpowder, in August 1839. The candle which Professor<br \/>\n    Faraday exhibited must therefore have been exposed to the action of salt<br \/>\n    water for upward of fifty-seven years.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>Mr. Field, of Lambeth, has supplied me abundantly with beautiful<br \/>\n  illustrations of the candle and its materials; I shall therefore now refer to<br \/>\n  them. And, first, there is the suet &#8211; the fat of the ox &#8211; Russian tallow, I<br \/>\n  believe, employed in the manufacture of these dips, which Gay-Lussac, or some<br \/>\n  one who intrusted him with his knowledge, converted into that beautiful<br \/>\n  substance, stearin, which you see lying beside it. A candle, you know, is not<br \/>\n  now a greasy thing like an ordinary tallow candle, but a clean thing, and you<br \/>\n  may almost scrape off and pulverize the drops which fall from it without<br \/>\n  soiling any thing. This is the process he adopted <SUP>2<\/SUP>: The fat or<br \/>\n  tallow is first boiled with quick-lime, and made into a soap, and then the<br \/>\n  soap is decomposed by sulphuric acid, which takes away the lime, and leaves<br \/>\n  the fat rearranged as stearic acid, while a quantity of glycerin is produced<br \/>\n  at the same time. Glycerin &#8211; absolutely a sugar, or a substance similar to<br \/>\n  sugar comes out of the tallow in this chemical change. The oil is then pressed<br \/>\n  out of it; and you see here this series of pressed cakes, showing how<br \/>\n  beautifully the impurities are carried out by the oily part as the pressure<br \/>\n  goes on increasing, and at last you have left that substance, which is melted,<br \/>\n  and cast into candles as here represented. The candle I have in my hand is a<br \/>\n  stearin candle, made of stearin from tallow in the way I have told you. Then<br \/>\n  here is a sperm candle, which comes from the purified oil of the spermaceti<br \/>\n  whale. Here, also, are yellow beeswax and refined beeswax, from which candles<br \/>\n  are made. Here, too, is that curious substance called paraffine, and some<br \/>\n  paraffine candles, made of paraffine obtained from the bogs of Ireland. I have<br \/>\n  here also a substance brought from Japan since we have forced an entrance into<br \/>\n  that out-of-the-way place &#8211; a sort of wax which a kind friend has sent me, and<br \/>\n  which forms a new material for the manufacture of candles.<\/P><br \/>\n  <BLOCKQUOTE><br \/>\n    <P>[Footnote 2: The fat or tallow consists of a chemical combination of<br \/>\n    fatty acids with glycerin. The lime unites with the palmitic, oleic, and<br \/>\n    stearic acids, and separates the glycerin. After washing, the insoluble lime<br \/>\n    soap is decomposed with hot dilute sulphuric acid. The melted fatty acids<br \/>\n    thus rise as an oil to the surface, when they are decanted. They are again<br \/>\n    washed and cast into thin plates, which, when cold, are placed between<br \/>\n    layers of cocoanut matting and submitted to intense hydraulic pressure. In<br \/>\n    this way the soft oleic acid is squeezed out, while the hard palmitic and<br \/>\n    stearic acids remain. These are farther purified by pressure at a higher<br \/>\n    temperature and washing in warm dilute sulphuric acid, when they are ready<br \/>\n    to be made into candles. These acids are harder and whiter than the fats<br \/>\n    from which they were obtained, while at the same time they are cleaner and<br \/>\n    more combustible.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>And how are these candles made? I have told you about dips, and I will show<br \/>\n  you how moulds are made. Let us imagine any of these candles to be made of<br \/>\n  materials which can be cast. &#8220;Cast!&#8221; you say. &#8220;Why, a candle is a thing that<br \/>\n  melts, and surely if you can melt it you can cast it.&#8221; Not so. It is<br \/>\n  wonderful, in the progress of manufacture, and in the consideration of the<br \/>\n  means best fitted to produce the required result, how things turn up which one<br \/>\n  would not expect beforehand. Candles can not always be cast. A wax candle can<br \/>\n  never be cast. It is made by a particular process which I can illustrate in a<br \/>\n  minute or two, but I must not spend much time on it. Wax is a thing which,<br \/>\n  burning so well, and melting so easily in a candle, can not be cast. However,<br \/>\n  let us take a material that can be cast. Here is a frame, with a number of<br \/>\n  moulds fastened in it. The first thing to be done is to put a wick through<br \/>\n  them. Here is one &#8211; a plaited wick, which does not require snuffing<br \/>\n  <SUP>3<\/SUP> supported by a little wire. It goes to the bottom, where it is<br \/>\n  pegged in &#8211; the little peg holding the cotton tight, and stopping the aperture<br \/>\n  so that nothing fluid shall run out. At the upper part there is a little bar<br \/>\n  placed across, which stretches the cotton and holds it in the mould. The<br \/>\n  tallow is then melted, and the moulds are filled. After a certain time, when<br \/>\n  the moulds are cool, the excess of tallow is poured off at one corner, and<br \/>\n  then cleaned off altogether, and the ends of the wick cut away. The candles<br \/>\n  alone then remain in the mould, and you have only to upset them, as I am<br \/>\n  doing, when out they tumble, for the candles are made in the form of cones,<br \/>\n  being narrower at the top than at the bottom: so that, what with their form<br \/>\n  and their own shrinking, they only need a little shaking, and out they fall.<br \/>\n  In the same way are made these candles of stearin and of paraffine. It is a<br \/>\n  curious thing to see how wax candles are made. A lot of cottons are hung upon<br \/>\n  frames, as you see here, and covered with metal tags at the ends to keep the<br \/>\n  wax from covering the cotton in those places. These are carried to a heater,<br \/>\n  where the wax is melted. As you see, the frames can turn round; and, as they<br \/>\n  turn, a man takes a vessel of wax and pours it first down one, and then the<br \/>\n  next, and the next, and so on. When he has gone once round, if it is<br \/>\n  sufficiently cool, he gives the first a second coat, and so on until they are<br \/>\n  all of the required thickness. When they have been thus clothed, or fed, or<br \/>\n  made up to that thickness, they are taken off and placed elsewhere. I have<br \/>\n  here, by the kindness of Mr. Field, several specimens of these candles. Here<br \/>\n  is one only half-finished. They are then taken down and well rolled upon a<br \/>\n  fine stone slab, and the conical top is moulded by properly shaped tubes, and<br \/>\n  the bottoms cut off and trimmed. This is done so beautifully that they can<br \/>\n  make candles in this way weighing exactly four or six to the pound, or any<br \/>\n  number they please.<\/P><\/p>\n<p>  <BLOCKQUOTE><br \/>\n    <P>[Footnote 3: A little borax or phosphorus salt is sometime added in order<br \/>\n    to make the ash fusible.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>We must not, however, take up more time about the mere manufacture, but go<br \/>\n  a little farther into the matter. I have not yet referred you to luxuries in<br \/>\n  candles (for there is such a thing as luxury in candles). See how beautifully<br \/>\n  these are colored; you see here mauve, magenta, and all the chemical colors<br \/>\n  recently introduced, applied to candles. You observe, also, different forms<br \/>\n  employed. Here is a fluted pillar most beautifully shaped; and I have also<br \/>\n  here some candles sent me by Mr. Pearsall, which are ornamented with designs<br \/>\n  upon them, so that, as they burn, you have, as it were, a glowing sun above,<br \/>\n  and bouquet of flowers beneath. All, however, that is fine and beautiful is<br \/>\n  not useful. These fluted candles, pretty as they are, are bad candles; they<br \/>\n  are bad because of their external shape. Nevertheless, I show you these<br \/>\n  specimens, sent to me from kind friends on all sides, that you may see what is<br \/>\n  done and what may be done in this or that direction; although, as I have said,<br \/>\n  when we come to these refinements, we are obliged to sacrifice a little in<br \/>\n  utility.<\/P><br \/>\n  <P>Now as to the light of the candle. We will light one or two, and set them<br \/>\n  at work in the performance of their proper functions. You observe a candle is<br \/>\n  a very different thing from a lamp. With a lamp you take a little oil, fill<br \/>\n  your vessel, put in a little moss or some cotton prepared by artificial means,<br \/>\n  and then light the top of the wick. When the flame runs down the cotton to the<br \/>\n  oil, it gets extinguished, but it goes on burning in the part above. Now I<br \/>\n  have no doubt you will ask how it is that the oil which will not burn of<br \/>\n  itself gets up to the top of the cotton, where it will burn. We shall<br \/>\n  presently examine that; but there is a much more wonderful thing about the<br \/>\n  burning of a candle than this. You have here a solid substance with no vessel<br \/>\n  to contain it; and how is it that this solid substance can get up to the place<br \/>\n  where the flame is? How is it that this solid gets there, it not being a<br \/>\n  fluid? or, when it is made a fluid, then how is it that it keeps together?<br \/>\n  This is a wonderful thing about a candle.<\/P><br \/>\n  <P>We have here a good deal of wind, which will help us in some of our<br \/>\n  illustrations, but tease us in others; for the sake, therefore, of a little<br \/>\n  regularity, and to simplify the matter, I shall make a quiet flame, for who<br \/>\n  can study a subject when there are difficulties in the way not belonging to<br \/>\n  it? Here is a clever invention of some costermonger or street-stander in the<br \/>\n  market-place for the shading of their candles on Saturday nights, when they<br \/>\n  are selling their greens, or potatoes, or fish. I have very often admired it.<br \/>\n  They put a lamp-glass round the candle, supported on a kind of gallery, which<br \/>\n  clasps it, and it can be slipped up and down as required. By the use of this<br \/>\n  lamp-glass, employed in the same way, you have a steady flame, which you can<br \/>\n  look at, and carefully examine, as I hope you will do, at home.<\/P><br \/>\n  <P>You see, then, in the first instance, that a beautiful cup is formed. As<br \/>\n  the air comes to the candle, it moves upward by the force of the current which<br \/>\n  the heat of the candle produces, and it so cools all the sides of the wax,<br \/>\n  tallow, or fuel as to keep the edge much cooler than the part within; the part<br \/>\n  within melts by the flame that runs down the wick as far as it can go before<br \/>\n  it is extinguished, but the part on the outside does not melt. If I made a<br \/>\n  current in one direction, my cup would be lop-sided, and the fluid would<br \/>\n  consequently run over; for the same force of gravity which holds worlds<br \/>\n  together holds this fluid in a horizontal position, and if the cup be not<br \/>\n  horizontal, of course the fluid will run away in guttering. You see,<br \/>\n  therefore, that the cup is formed by this beautifully regular ascending<br \/>\n  current of air playing upon all sides, which keeps the exterior of the candle<br \/>\n  cool. No fuel would serve for a candle which has not the property of giving<br \/>\n  this cup, except such fuel as the Irish bogwood, where the material itself is<br \/>\n  like a sponge and holds its own fuel. You see now why you would have had such<br \/>\n  a bad result if you were to burn these beautiful candles that I have shown<br \/>\n  you, which are irregular, intermittent in their shape, and can not, therefore,<br \/>\n  have that nicely-formed edge to the cup which is the great beauty in a candle.<br \/>\n  I hope you will now see that the perfection of a process &#8211; that is, its<br \/>\n  utility &#8211; is the better point of beauty about it. It is not the gest looking<br \/>\n  thing, but the best acting thing, which is the most advantageous to us. This<br \/>\n  good-looking candle is a bad-burning one. There will be a guttering round<br \/>\n  about it because of the irregularity of the stream of air and the badness of<br \/>\n  the cup which is formed thereby. You may see some pretty examples (and I trust<br \/>\n  you will notice these instances) of the action of the ascending current when<br \/>\n  you have a little gutter run down the side of a candle, making it thicker<br \/>\n  there than it is elsewhere. As the candle goes on burning, that keeps its<br \/>\n  place and forms a little pillar sticking up by the side, because, as it rises<br \/>\n  higher above the rest of the wax or fuel, the air gets better round it, and it<br \/>\n  is more cooled and better able to resist the action of the heat at a little<br \/>\n  distance. Now the greatest mistakes and faults with regard to candles, as in<br \/>\n  many other things, often bring with them instruction which we should not<br \/>\n  receive if they had not occurred. We come here to be philosophers, and I hope<br \/>\n  you will always remember that whenever a result happens, especially if it be<br \/>\n  new, you should say, &#8220;What is the cause? Why does it occur?&#8221; and you will, in<br \/>\n  the course of time, find out the reason.<\/P><\/p>\n<p>  <P>Then there is another point about these candles which will answer a<br \/>\n  question &#8211; that is, as to the way in which this fluid gets out of the cup, up<br \/>\n  the wick, and into the place of combustion. You know that the flames on these<br \/>\n  burning wicks in candles made of beeswax, stearin, or spermaceti, do not run<br \/>\n  down to the wax or other matter, and melt it all away, but keep to their own<br \/>\n  right place. They are fenced off from the fluid below, and do not encroach on<br \/>\n  the cup at the sides. I can not imagine a more beautiful example than the<br \/>\n  condition of adjustment under which a candle makes one part subserve to the<br \/>\n  other to the very end of its action. A combustible thing like that, burning<br \/>\n  away gradually, never being intruded upon by the flame, is a very beautiful<br \/>\n  sight, especially when you come to learn what a vigorous thing flame is &#8211; what<br \/>\n  power it has of destroying the wax itself when it gets hold of it, and of<br \/>\n  disturbing its proper form if it come only too near.<\/P><br \/>\n  <P>But how does the flame get hold of the fuel? There is a beautiful point<br \/>\n  about that &#8211; capillary attraction. <SUP>4<\/SUP> &#8220;Capillary attraction!&#8221; you<br \/>\n  say &#8211; &#8220;the attraction of hairs.&#8221; Well, never mind the name; it was given in<br \/>\n  old times, before we had a good understanding of what the real power was. It<br \/>\n  is by what is called capillary attraction that the fuel is conveyed to the<br \/>\n  part where combustion goes on, and is deposited there, not in a careless way,<br \/>\n  but very beautifully in the very midst of the centre of action, which takes<br \/>\n  place around it. Now I am going to give you one or two instances of capillary<br \/>\n  attraction. It is that kind of action or attraction which makes two things<br \/>\n  that do not dissolve in each other still hold together. When you wash your<br \/>\n  hands, you wet them thoroughly; you take a little soap to make the adhesion<br \/>\n  better, and you find your hands remain wet. This is by that kind of attraction<br \/>\n  of which I am about to speak. And, what is more, if your hands are not soiled<br \/>\n  (as they almost always are by the usages of life), if you put your finger into<br \/>\n  a little warm water, the water will creep a little way up the finger, though<br \/>\n  you may not stop to examine it. I have here a substance which is rather porous<br \/>\n  &#8211; a column of salt &#8211; and I will pour into the plate at the bottom, not water,<br \/>\n  as it appears, but a saturated solution of salt which can not absorb more, so<br \/>\n  that the action which you see will not be due to its dissolving any thing. We<br \/>\n  may consider the plate to be the candle, and the salt the wick, and this<br \/>\n  solution the melted tallow. (I have colored the fluid, that you may see the<br \/>\n  action better.) You observe that, now I pour in the fluid, it rises and<br \/>\n  gradually creeps up the salt higher and higher; and provided the column does<br \/>\n  not tumble over, it will go to the top. If this blue solution were<br \/>\n  combustible, and we were to place a wick at the top of the salt, it would burn<br \/>\n  as it entered into the wick. It is a most curious thing to see this kind of<br \/>\n  action taking place, and to observe how singular some of the circumstances are<br \/>\n  about it. When you wash your hands, you take a towel to wipe off the water;<br \/>\n  and it is by that kind of wetting, or that kind of attraction which makes the<br \/>\n  towel become wet with water, that the wick is made wet with the tallow. I have<br \/>\n  known some careless boys and girls (indeed, I have known it happen to careful<br \/>\n  people as well) who, having washed their hands and wiped them with a towel,<br \/>\n  have thrown the towel over the side of the basin, and before long it has drawn<br \/>\n  all the water out of the basin and conveyed it to the floor, because it<br \/>\n  happened to be thrown over the side in such a way as to serve the purpose of a<br \/>\n  siphon. <SUP>5<\/SUP> That you may the better see the way in which the<br \/>\n  substances act one upon another, I have here a vessel made of wire gauze<br \/>\n  filled with water, and you may compare it in its action to the cotton in one<br \/>\n  respect, or to a piece of calico in the other. In fact, wicks are sometimes<br \/>\n  made of a kind of wire gauze. You will observe that this vessel is a porous<br \/>\n  thing; for if I pour a little water on to the top, it will run out at the<br \/>\n  bottom. You would be puzzled for a good while if I asked you what the state of<br \/>\n  this vessel is, what is inside it, and why it is there? The vessels is full of<br \/>\n  water, and yet you see the water goes in and runs out as if it were empty. In<br \/>\n  order to prove this to you, I have only to empty it. The reason is this: the<br \/>\n  wire, being once wetted, remains wet; the meshes are so small that the fluid<br \/>\n  is attracted so strongly from the one side to the other, as to remain in the<br \/>\n  vessel, although it is porous. In like manner, the particles of melted tallow<br \/>\n  ascend the cotton and get to the top: other particles then follow by their<br \/>\n  mutual attraction for each other, and as they reach the flame they are<br \/>\n  gradually burned.<\/P><br \/>\n  <BLOCKQUOTE><br \/>\n    <P>[Footnote 4: Capillary attraction or repulsion is the cause which<br \/>\n    determines the ascent or descent of a fluid in a capillary tube. If a piece<br \/>\n    of thermometer tubing, open at each end, be plunged into water, the latter<br \/>\n    will instantly rise in the tube considerably above its external level. If,<br \/>\n    on the other hand, the tube be plunged into mercury, a repulsion instead of<br \/>\n    attraction will be exhibited, and the level of the mercury will be lower in<br \/>\n    the tube than it is outside.]<\/P><\/BLOCKQUOTE><\/p>\n<p>  <BLOCKQUOTE><br \/>\n    <P>[Footnote 5: The late Duke of Sussex was, we believe, the first to show<br \/>\n    that a prawn might be washed upon this principle. If the tail, after pulling<br \/>\n    off the fan part, be placed in a tumbler of water, and the head be allowed<br \/>\n    to hang over the outside, the water will be sucked up the tail by capillary<br \/>\n    attraction, and will continue to run out through the head until the water in<br \/>\n    the glass has sunk so low the tail ceases to dip into it.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>Here is another application of the same principle. You see this bit of<br \/>\n  cane. I have seen boys about the streets, who are very anxious to appear like<br \/>\n  men, take a piece of cane, and light it, and smoke it, as an imitation of a<br \/>\n  cigar. They are enable to do so by the permeability of the cane in one<br \/>\n  direction, and by its capillarity. If I place this piece of cane on a plate<br \/>\n  containing some camphene (which is very much like paraffine in its general<br \/>\n  character), exactly in the same manner as the blue fluid rose through the salt<br \/>\n  will this fluid rise through the piece of cane. There being no pores at the<br \/>\n  side, the fluid can not go in that direction, but must pass through its<br \/>\n  length. Already the fluid is at the top of the cane; now I can light it and<br \/>\n  make it serve as a candle. The fluid has risen by the capillary attraction of<br \/>\n  the piece of cane, just as it does through the cotton in the candle.<\/P><br \/>\n  <P>Now the only reason why the candle does not burn all down the side of the<br \/>\n  wick is that the melted tallow extinguishes the flame. You know that a candle,<br \/>\n  if turned upside down, so as to allow the fuel to run upon the wick, will be<br \/>\n  put out. The reason is, that the flame has not had time to make the fuel hot<br \/>\n  enough to burn, as it does above, where it is carried in small quantities into<br \/>\n  the wick, and has all the effect of the heat exercised upon it.<\/P><br \/>\n  <P>There is another condition which you must learn as regards the candle,<br \/>\n  without which you would not be able fully to understand the philosophy of it,<br \/>\n  and that is the vaporous condition of the fuel. In order that you may<br \/>\n  understand that, let me show you a very pretty but very commonplace<br \/>\n  experiment. If you blow a candle out cleverly, you will see the vapor rise<br \/>\n  from it. You have, I know, often smelt the vapor of a blown-out candle, and a<br \/>\n  very bad smell it is; but if you blow it out cleverly you will be able to see<br \/>\n  pretty well the vapor into which this solid matter is transformed. I will blow<br \/>\n  out one of these candles in such a way as not to disturb the air around it by<br \/>\n  the continuing action of my breath; and now, if I hold a lighted taper two or<br \/>\n  three inches from the wick, you will observe a train of fire going through the<br \/>\n  air till it reaches the candle. I am obliged to be quick and ready, because if<br \/>\n  I allow the vapor time to cool, it becomes condensed into a liquid or solid,<br \/>\n  or the stream of combustible matter gets disturbed.<\/P><br \/>\n  <P>Now as to the shape or form of the flame. It concerns us much to know about<br \/>\n  the condition which the matter of the candle finally assumes at the top of the<br \/>\n  wick, where you have such beauty and brightness as nothing but combustion or<br \/>\n  flame can produce. You have the glittering beauty of gold and silver, and the<br \/>\n  still higher lustre of jewels like the ruby and diamond; but none of these<br \/>\n  rival the brilliancy and beauty of flame. What diamond can shine like flame?<br \/>\n  It owes its lustre at nighttime to the very flame shining upon it. The flame<br \/>\n  shines in darkness, but the light which the diamond has is as nothing until<br \/>\n  the flame shines upon it, when it is brilliant again. The candle alone shines<br \/>\n  by itself and for itself, or for those who have arranged the materials. Now<br \/>\n  let us look a little at the form of the flame as you see it under the glass<br \/>\n  shade. It is steady and equal, and its general form is that which is<br \/>\n  represented in the diagram, varying with atmospheric disturbances, and also<br \/>\n  varying according to the size of the candle. It is a bright oblong, brighter<br \/>\n  at the top than toward the bottom, with the wick in the middle, and, besides<br \/>\n  the wick in the middle, certain darker parts towards the bottom, where the<br \/>\n  ignition is not so perfect as in the part above. I have a drawing here,<br \/>\n  sketched many years ago by Hooker, when he made his investigations. It is the<br \/>\n  drawing of the flame of a lamp, but it will apply to the flame of a candle.<br \/>\n  The cup of the candle is the vessel or lamp; the melted spermaceti is the oil;<br \/>\n  and the wick is common to both. Upon that he sets this little flame, and then<br \/>\n  he represents what is true, a certain quantity of matter rising about it which<br \/>\n  you do not see, and which, if you have not been here before, or are not<br \/>\n  familiar with the subject, you will not know of. He has here represented the<br \/>\n  parts of the surrounding atmosphere that are very essential to the flame, and<br \/>\n  that are always present with it. There is a current formed, which draws the<br \/>\n  flame out; for the flame which you see is really drawn out by the current, and<br \/>\n  drawn upward to a great height, just as Hooker has here shown you by that<br \/>\n  prolongation of the current in the diagram. You may see this by taking a<br \/>\n  lighted candle, and putting it in the sun so as to get its shadow thrown on a<br \/>\n  piece of paper. How remarkable it is that that thing which is light enough to<br \/>\n  produce shadows of other objects can be made to throw its own shadow on a<br \/>\n  piece of white paper or card, so that you can actually see streaming round the<br \/>\n  flame something which is not part of the flame, but is ascending and drawing<br \/>\n  the flame upward. Now I am going to imitate the sunlight by applying the<br \/>\n  voltaic battery to the electric lamp. You now see our sun and its great<br \/>\n  luminosity; and by placing a candle between it and the screen, we get the<br \/>\n  shadow of the flame. You observe the shadow of the candle and of the wick;<br \/>\n  then there is a darkish part, as represented in the diagram, and then a part<br \/>\n  which is more distinct. Curiously enough, however, what we see in the shadow<br \/>\n  as the darkest part of the flame is, in reality, the brightest part; and here<br \/>\n  you see streaming upward the ascending current of hot air, as shown by Hooker,<br \/>\n  which draws out the flame, supplies it with air, and cools the sides of the<br \/>\n  cup of melted fuel.<\/P><\/p>\n<p>  <P>I can give you here a little farther illustration, for the purpose of<br \/>\n  showing you how flame goes up or down according to the current. I have here a<br \/>\n  flame &#8211; it is not a candle flame &#8211; but you can, no doubt, by this time<br \/>\n  generalize enough to be able to compare one thing with another. What I am<br \/>\n  about to do is to change the ascending current that takes the flame upward<br \/>\n  into a descending current. This I can easily do by the little apparatus you<br \/>\n  see before me. The flame, as I have said, is not a candle flame, but it is<br \/>\n  produced by alcohol, so that it shall not smoke too much. I will also color<br \/>\n  the flame with another substance <SUP>6<\/SUP>, so that you may trace its<br \/>\n  course; for, with the spirit alone, you could hardly see well enough to have<br \/>\n  the opportunity of tracing its direction. By lighting this spirit of wine we<br \/>\n  have then a flame produced, and you observe that when held in the air it<br \/>\n  naturally goes upward. You understand now, easily enough, why flames go up<br \/>\n  under ordinary circumstances: it is because of the draught of air by which the<br \/>\n  combustion is formed. But now, by blowing the flame down, you see I am enabled<br \/>\n  to make it go downward into this little chimney, the direction of the current<br \/>\n  being changed. Before we have concluded this course of lectures we shall show<br \/>\n  you a lamp in which the flame goes up and the smoke goes down, or the flame<br \/>\n  goes down and the smoke goes up. You see, then, that we have the power in this<br \/>\n  way of varying the flame in different directions.<\/P><br \/>\n  <BLOCKQUOTE><br \/>\n    <P>[Footnote 6: The alcohol had chloride of copper dissolved in it: this<br \/>\n    produces a beautiful green flame.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>There are now some other points that I must bring before you. Many of the<br \/>\n  flames you see here vary very much in their shape by the currents of air<br \/>\n  blowing around them in different directions; but we can, if we like, make<br \/>\n  flames so that they will look like fixtures, and we can photograph them<br \/>\n  indeed, we have to photograph them &#8211; so that they become fixed to us, if we<br \/>\n  wish to find out every thing concerning them. That, however, is not the only<br \/>\n  thing I wish to mention. If I take a flame sufficiently large, it does not<br \/>\n  keep that homogeneous, that uniform condition of shape, but it breaks out with<br \/>\n  a power of life which is quite wonderful. I am about to use another kind of<br \/>\n  fuel, but one which is truly and fairly a representative of the wax or tallow<br \/>\n  of a candle. I have here a large ball of cotton, which will serve as a wick.<br \/>\n  And, now that I have immersed it in spirit and applied a light to it, in what<br \/>\n  way does it differ from an ordinary candle? Why, it differs very much in one<br \/>\n  respect, that we have a vivacity and power about it, a beauty and a life<br \/>\n  entirely different from the light presented by a candle. You see those fine<br \/>\n  tongues of flame rising up. You have the same general disposition of the mass<br \/>\n  of the flame from below upward; but, in addition to that, you have this<br \/>\n  remarkable breaking out into tongues which you do not perceive in the case of<br \/>\n  a candle. Now, why is this? I must explain it to you, because, when you<br \/>\n  understand that perfectly, you will be able to follow me better in what I have<br \/>\n  to say hereafter. I suppose some here will have made for themselves the<br \/>\n  experiment I am going to show you. Am I right in supposing that any body here<br \/>\n  has played at snapdragon? I do not know a more beautiful illustration of the<br \/>\n  philosophy of flame, as to a certain part of its history, than the game of<br \/>\n  snapdragon. First, here is the dish; and let me say, that when you play<br \/>\n  snapdragon properly you ought to have the dish well warmed; you ought also to<br \/>\n  have warm plums, and warm brandy, which, however, I have not got. When you<br \/>\n  have put the spirit into the dish, you have the cup and the fuel; and are not<br \/>\n  the raisins acting like the wicks? I now throw the plums into the dish, and<br \/>\n  light the spirit, and you see those beautiful tongues of flame that I refer<br \/>\n  to. You have the air creeping in over the edge of the dish forming these<br \/>\n  tongues. Why? Because, through the force of the current and the irregularity<br \/>\n  of the action of the flame, it can not flow in one uniform stream. The air<br \/>\n  flows in so irregularly that you have what would otherwise be a single image<br \/>\n  broken up into a variety of forms, and each of these little tongues has an<br \/>\n  independent existence of its own. Indeed, I might say, you have here a<br \/>\n  multitude of independent candles. You must not imagine, because you see these<br \/>\n  tongues all at once, that the flame is of this particular shape. A flame of<br \/>\n  that shape is never so at any one time. Never is a body of flame, like that<br \/>\n  which you just saw rising from the ball, of the shape it appears to you. I<br \/>\n  consists of a multitude of different shapes, succeeding each other so fast<br \/>\n  that the eye is only able to take cognizance of them all at once. In former<br \/>\n  times I purposely analyzed a flame of that general character, and the diagram<br \/>\n  shows you the different parts of which it is composed. They do not occur all<br \/>\n  at once; it is only because we see these shapes in such rapid succession that<br \/>\n  they seem to us to exist all at one time.<\/P><br \/>\n  <P>It is too bad that we have not got farther than my game of snapdragon; but<br \/>\n  we must not, under any circumstances, keep you beyond your time. It will be a<br \/>\n  lesson to me in future to hold you more strictly to the philosophy of the<br \/>\n  thing than to take up your time so much with these illustrations.<\/P><br \/>\n  <P><BR><STRONG><A name=\"Lecture II\">Lecture II<\/A>: Brightness Of<br \/>\n  The Flame &#8211; Air Necessary For Combustion &#8211; Production Of<br \/>\n  Water<\/STRONG><\/P><\/p>\n<p>  <P>We were occupied the last time we met in considering the general character<br \/>\n  and arrangement as regards the fluid portion of a candle, and the way in which<br \/>\n  that fluid got into the place of combustion. You see, when we have a candle<br \/>\n  burning fairly in a regular, steady atmosphere, it will have a shape something<br \/>\n  like the one shown in the diagram, and will look pretty uniform, although very<br \/>\n  curious in its character. And now I have to ask your attention to the means by<br \/>\n  which we are enabled to ascertain what happens in any particular part of the<br \/>\n  flame; why it happens; what it does in happening; and where, after all, the<br \/>\n  whole candle goes to; because, as you know very well, a candle being brought<br \/>\n  before us and burned, disappears, if burned properly, without the least trace<br \/>\n  of dirt in the candle stick, and this is a very curious circumstance. In<br \/>\n  order, then, to examine this candle carefully, I have arranged certain<br \/>\n  apparatus, the use of which you will see as I go on. Here is a candle; I am<br \/>\n  about to put the end of this glass tube into the middle of the flame &#8211; into<br \/>\n  that part which old Hooker has represented in the diagram as being rather<br \/>\n  dark, and which you can see at any time if you will look at a candle<br \/>\n  carefully, without blowing it about. We will examine this dark part first.<\/P><br \/>\n  <P>Now I take this bent glass tube, and introduce one end into that part of<br \/>\n  the flame, and you see at once that something is coming from the flame, out at<br \/>\n  the other end of the tube; and if I put a flask there, and leave it for a<br \/>\n  little while, you will see that something from the middle part of the flame is<br \/>\n  gradually drawn out, and goes through the tube, and into that flask, and there<br \/>\n  behaves very differently from what it does in the open air. It not only<br \/>\n  escapes from the end of the tube, but falls down to the bottom of the flask<br \/>\n  like a heavy substance, as indeed it is. We find that this is the wax of<br \/>\n  experiment, if there is not too much disturbance, there will always be a ring.<br \/>\n  This is a good experiment for you to make at home. Take a strip of paper, have<br \/>\n  the air in the room quiet, and put the piece of paper right across the middle<br \/>\n  of the flame &#8211; (I must not talk while I make the experiment) &#8211; and you will<br \/>\n  find that it is burnt in two places, and that it is not burnt, or very little<br \/>\n  so, in the middle; and when you have tried the experiment once or twice, so as<br \/>\n  to make it nicely, you will be very interested to see where the heat is, and<br \/>\n  to find that it is where the air and the fuel come together.<\/P><br \/>\n  <P>This is most important for us as we proceed with out subject. Air is<br \/>\n  absolutely necessary for combustion; and, what is more, I must have you<br \/>\n  understand that fresh air is necessary, or else we should be imperfect in our<br \/>\n  reasoning and our experiments. Here is a jar of air; I place it over a candle,<br \/>\n  and it burns very nicely in it at first, showing that what I have said about<br \/>\n  it is true; but there will soon be a change. See how the flame is drawing<br \/>\n  upward, presently fading, and at last going out. And going out, why? Not<br \/>\n  because it wants air merely, for the jar is as full now as it was before; but<br \/>\n  it wants pure, fresh air. The jar is full of air, partly changed, partly not<br \/>\n  changed; but it does not contain sufficient of the fresh air which is<br \/>\n  necessary for the combustion of a candle. These are all points which we, as<br \/>\n  young chemists, have to gather up; and if we look a little more closely into<br \/>\n  this kind of action, we shall find certain steps of reasoning extremely<br \/>\n  interesting. For instance, here is the oil-lamp I showed you &#8211; an excellent<br \/>\n  lamp for our experiments &#8211; the old Argand lamp. I now make it like a candle<br \/>\n  (obstructing the passage of air into the centre of the flame); there is the<br \/>\n  cotton; there is the oil rising up in it, and there is the conical flame. It<br \/>\n  burns poorly because there is a partial restraint of air. I have allowed no<br \/>\n  air to get to it save around the outside of the flame, and it does not burn<br \/>\n  well. I can not admit more air from the outside, because the wick is large;<br \/>\n  but if, as Argand did so cleverly, I open a passage to the middle of the<br \/>\n  flame, and so let air come in there, you will see how much more beautifully it<br \/>\n  burns. If I shut the air off, look how it smokes; and why? We have now some<br \/>\n  very interesting points to study: we have the case of the combustion of a<br \/>\n  candle; we have the case of a candle being put out by the want of air; and we<br \/>\n  have now the case of imperfect combustion, and this is to us so interesting<br \/>\n  that I want you to understand it as thoroughly as you do the case of a candle<br \/>\n  burning in its best possible manner. I will now make a great flame, because we<br \/>\n  need the largest possible illustrations. Here is a larger wick (burning<br \/>\n  turpentine on a ball of cotton). All these things are the same as candles,<br \/>\n  after all. If we have larger wicks, we must have a larger supply of air, or we<br \/>\n  shall have less perfect combustion. Look, now, at this black substance going<br \/>\n  up into the atmosphere; there is a regular stream of it. I have provided means<br \/>\n  to carry off the imperfectly burned part, lest it should annoy you. Look at<br \/>\n  the soots that fly off from the flame; see what an imperfect combustion it is,<br \/>\n  because it can not get enough air. What, then, is happening? Why, certain<br \/>\n  things which are necessary to the combustion of a candle are absent, and very<br \/>\n  bad results are accordingly produced; but we see what happens to a candle when<br \/>\n  it is burnt in a pure and proper state of air. At the time when I showed you<br \/>\n  this charring by the ring of flame on the one side of the paper, I might have<br \/>\n  also shown you, by turning to the other side, that the burning of a candle<br \/>\n  produces the same kind of soot &#8211; charcoal, or carbon.<\/P><br \/>\n  <P>But, before I show that, let me explain to you, as it is quite necessary<br \/>\n  for our purpose, that, though I take a candle, and give you, as the general<br \/>\n  result, its combustion in the form of a flame, we must see whether combustion<br \/>\n  is always in this condition, or whether there are other conditions of flame;<br \/>\n  and we shall soon discover that there are, and that they are most important to<br \/>\n  us. I think, perhaps, the best illustration of such a point to us, as<br \/>\n  juveniles, is to show the result of strong contrast. Here is a little<br \/>\n  gunpowder. You know that gunpowder burns with flame; we may fairly call it<br \/>\n  flame. It contains carbon and other materials, which altogether cause it to<br \/>\n  burn with a flame. And here is some pulverized iron, or iron filings. Now I<br \/>\n  purpose burning these two things together. I have a little mortar in which I<br \/>\n  will mix them. (Before I go into these experiments, let me hope that none of<br \/>\n  you, by trying to repeat them for fun&#8217;s sake, will do any harm. These things<br \/>\n  may all be very properly used if you take care, but without that much mischief<br \/>\n  will be done.) Well, then here is a little gunpowder, which I put at the<br \/>\n  bottom of that little wooden vessel, and mix the iron filings up with it, my<br \/>\n  object being to make the gunpowder set fire to the filings and burn them in<br \/>\n  the air, and thereby show the difference between substances burning with flame<br \/>\n  and not with flame. Here is the mixture; and when I set fire to it you must<br \/>\n  watch the combustion, and you will see that it is of two kinds. You will see<br \/>\n  the gunpowder burning with a flame and the filings thrown up. You will see<br \/>\n  them burning, too, but without the production of flame. They will each burn<br \/>\n  separately. [The lecturer then ignited the mixture.] There is the gunpowder,<br \/>\n  which burns with a flame, and there are the filings: they burn with a<br \/>\n  different kind of combustion. You see, then, these two great distinctions; and<br \/>\n  upon these differences depend all the utility and all the beauty of flame<br \/>\n  which we use for the purpose of giving out light. When we use oil, or gas, or<br \/>\n  candle for the purpose of illumination, their fitness all depends upon these<br \/>\n  different kinds of combustion.<\/P><br \/>\n  <P>There are such curious conditions of flame that it requires some cleverness<br \/>\n  and nicety of discrimination to distinguish the kinds of combustion one from<br \/>\n  another. For instance, here is a powder which is very combustible, consisting,<br \/>\n  as you see, of separate little particles. It is called lycopodium,<br \/>\n  <SUP>7<\/SUP> and each of these particles can produce a vapor, and produce its<br \/>\n  own flame; but, to see them burning, you would imagine it was all one flame. I<br \/>\n  will now set fire to a quantity, and you will see the effect. We saw a cloud<br \/>\n  of flame, apparently in one body; but that rushing noise [referring to the<br \/>\n  sound produced by the burning] was a proof that the combustion was not a<br \/>\n  continuous or regular one. This is the lightning of the pantomimes, and a very<br \/>\n  good imitation. [The experiment was twice repeated by blowing lycopodium from<br \/>\n  a glass tube through a spirit flame.] This is not an example of combustion<br \/>\n  like that of the filings I have been speaking of, to which we must now<br \/>\n  return.<\/P><\/p>\n<p>  <BLOCKQUOTE><br \/>\n    <P>[Footnote 7: Lycopodium is a yellowish powder found in the fruit of the<br \/>\n    club moss (Lycopodium clavatum). It is used in fireworks.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>Suppose I take a candle and examine that part of it which appears brightest<br \/>\n  to our eyes. Why, there I get these black particles, which already you have<br \/>\n  seen many times evolved from the flame, and which I am now about to evolve in<br \/>\n  a different way. I will take this candle and clear away the gutterage, which<br \/>\n  occurs by reason of the currents of air, and if I now arrange the glass tube<br \/>\n  so as just to dip into this luminous part, as in our first experiment, only<br \/>\n  higher, you see the result. In place of having the same white vapor that you<br \/>\n  had before, you will now have a black vapor. There is goes, as black as ink.<br \/>\n  It is certainly very different from the white vapor; and when we put a light<br \/>\n  to it we shall find that it does not burn, but that it puts the light out.<br \/>\n  Well, these particles, as I said before, are just the smoke of the candle; and<br \/>\n  this brings to mind that old employment which Dean Swift recommended to<br \/>\n  servants for their amusement, namely writing on the ceiling of a room with a<br \/>\n  candle. But what is that black substance? Why, it is the same carbon which<br \/>\n  exists in the candle. How comes it out of the candle? It evidently existed in<br \/>\n  the candle, or else we should not have had it here. And now I want you to<br \/>\n  follow me in this explanation. You would hardly think that all those<br \/>\n  substances which fly about London, in the form of soots and blacks, are the<br \/>\n  very beauty and life of the flame, and which are burned in it as those iron<br \/>\n  filings were burned here. Here is a piece of wire gauze, which will not let<br \/>\n  the flame go through it; and I think you will see, almost immediately, that<br \/>\n  when I bring it low enough to touch that part of the flame which is otherwise<br \/>\n  so bright, it quells and quinches it at once, and allows a volume of smoke to<br \/>\n  rise up.<\/P><br \/>\n  <P>I want you now to follow me in this point &#8211; that whenever a substance<br \/>\n  burns, as the iron filings burnt in the flame of gunpowder, without assuming<br \/>\n  the vaporous state (whether it becomes liquid or remains solid), it becomes<br \/>\n  exceedingly luminous. I have here taken three or four examples apart from the<br \/>\n  candle on purpose to illustrate this point to you, because what I have to say<br \/>\n  is applicable to all substances, whether they burn or whether they do not burn<br \/>\n  &#8211; that they are exceedingly bright if they retain their solid state, and that<br \/>\n  it is to this presence of solid particles in the candle flame that it owes its<br \/>\n  brilliancy.<\/P><br \/>\n  <P>Here is a platinum wire, a body which does not change by heat. If I heat it<br \/>\n  in this flame, see how exceedingly luminous it becomes. I will make the flame<br \/>\n  dim for the purpose of giving a little light only, and yet you will see that<br \/>\n  the heat which it can give to that platinum wire, though far less than the<br \/>\n  heat it has itself, is able to raise the platinum wire to a far higher state<br \/>\n  of effulgence. This flame has carbon in it; but I will take one that has no<br \/>\n  carbon in it. There is a material, a kind of fuel &#8211; a vapor, or gas, whichever<br \/>\n  you like to call it &#8211; in that vessel, and it has no solid particles in it; so<br \/>\n  I take that because it is an example of flame itself burning without any solid<br \/>\n  matter whatever; and if I now put this solid substance in it, you see what an<br \/>\n  intense heat it has, and how brightly it causes the solid body to glow. This<br \/>\n  is the pipe through which we convey this particular gas, which we call<br \/>\n  hydrogen, and which you shall know all about the next time we meet. And here<br \/>\n  is a substance called oxygen, by means of which this hydrogen can burn; and<br \/>\n  although we produce, by their mixture, far greater heat <SUP>8<\/SUP> than you<br \/>\n  can obtain from the candle, yet there is very little light. If, however, I<br \/>\n  take a solid substance, and put that into it, we produce an intense light. If<br \/>\n  I take a piece of lime, a substance which will not burn, and which will not<br \/>\n  vaporize by the heat (and because it does not vaporize remains solid, and<br \/>\n  remains heated), you will soon observe what happens as to its glowing. I have<br \/>\n  here a most intense heat produced by the burning of hydrogen in contact with<br \/>\n  the oxygen; but there is as yet very little light &#8211; not for want of heat, but<br \/>\n  for want of particles which can retain their solid state; but when I hold this<br \/>\n  piece of lime in the flame of the hydrogen as it burns in the oxygen, see how<br \/>\n  it glows! This is glorious lime light, which rivals the voltaic light, and<br \/>\n  which is almost equal to sunlight. I have here a piece of carbon or charcoal,<br \/>\n  which will burn and give us light exactly in the same manner as if it were<br \/>\n  burnt as part of a candle. The heat that is in the flame of a candle<br \/>\n  decomposes the vapor of the wax, and sets free the carbon particles; they rise<br \/>\n  up heated and glowing as this now glows, and then enter into the air. But the<br \/>\n  particles, when burnt, never pass off from a candle in the form of carbon.<br \/>\n  They go off into the air as a perfectly invisible substance, about which we<br \/>\n  shall know hereafter.<\/P><\/p>\n<p>  <BLOCKQUOTE><br \/>\n    <P>[Footnote 8: Bunsen has calculated that the temperature of the<br \/>\n    oxyhydrogen blowpipe is 8061C. Hydrogen burning in air has a temperature of<br \/>\n    3259C., and coal gas in air, 2350C]<\/P><\/BLOCKQUOTE><br \/>\n  <P>Is it not beautiful to think that such a process is going on, and that such<br \/>\n  a dirty things as charcoal can become so incandescent? You see it comes to<br \/>\n  this &#8211; that all bright flames contain these solid particles; all things that<br \/>\n  burn and produce solid particles, either during the time they are burning, as<br \/>\n  in the candle, or immediately after being burnt, as in the case of the<br \/>\n  gunpowder and iron filings &#8211; all these things give us this glorious and<br \/>\n  beautiful light.<\/P><br \/>\n  <P>I will give you a few illustrations. Here is a piece of phosphorus, which<br \/>\n  burns with a bright flame. Very well; we may now conclude that phosphorus will<br \/>\n  produce, either at the moment that it is burning or afterwards, these solid<br \/>\n  particles. Here is the phosphorus lighted, and I cover it over with this glass<br \/>\n  for the purpose of keeping in what is produced. What is all that smoke? That<br \/>\n  smoke consists of those very particles which are produced by the combustion of<br \/>\n  the phosphorus. Here, again, are two substances. This is chlorate of potassa,<br \/>\n  and this other sulphuret of antimony. I shall mix these together a little, and<br \/>\n  then they may be burnt in many ways. I shall touch them with a drop of<br \/>\n  sulphuric acid, for the purpose of giving you an illustration of chemical<br \/>\n  action, and they will instantly burn. <SUP>9<\/SUP> [The lecturer then ignited<br \/>\n  the mixture by means of sulphuric acid.] Now, from the appearance of things,<br \/>\n  you can judge for yourselves whether they produce solid matter in burning. I<br \/>\n  have given you the train of reasoning which will enable you to say whether<br \/>\n  they do or do not; for what is this bright flame but the solid particles<br \/>\n  passing off?<\/P><br \/>\n  <BLOCKQUOTE><br \/>\n    <P>[Footnote 9: The following is the action of the sulphuric in inflaming<br \/>\n    the mixture of sulphuret of antimony and chlorate of potassa. A portion of<br \/>\n    the latter is decomposed by the sulphuric acid into oxide of chlorine,<br \/>\n    bisulphate of potassa, and perchlorate of potassa. The oxide of chlorine<br \/>\n    inflames the sulphuret of antimony, which is a combustible body, and the<br \/>\n    whole mass instantly bursts into flame.]<\/P><\/BLOCKQUOTE><\/p>\n<p>  <P>Mr. Anderson has in the furnace a very hot crucible. I am about to throw<br \/>\n  into it some zinc filings, and they will burn with flame like gunpowder. I<br \/>\n  make this experiment because you can make it well at home. Now I want you to<br \/>\n  see what will be the result of the combustion of this zinc. Here it is burning<br \/>\n  &#8211; burning beautifully like a candle, I may say. But what is all that smoke,<br \/>\n  and what are those little clouds of wool which will come to you if you can not<br \/>\n  come to them, and make themselves sensible to you in the form of the old<br \/>\n  philosophic wool, as it was called? We shall have left in that crucible, also,<br \/>\n  a quantity of this woolly matter. But I will take a piece of this same zinc,<br \/>\n  and make an experiment a little more closely at home, as it were. You will<br \/>\n  have here the same thing happening. Here is the piece of zinc; there [pointing<br \/>\n  to a jet of hydrogen] is the furnace, and we will set to work and try and burn<br \/>\n  the metal. It glows, you see; there is the combustion; and there is the white<br \/>\n  substance into which it burns. And so, if I take that flame of hydrogen as the<br \/>\n  representative of a candle, and show you a substance like zinc burning in the<br \/>\n  flame, you will see that it was merely during the action of combustion that<br \/>\n  this substance glowed &#8211; while it was kept hot; and if I take a flame of<br \/>\n  hydrogen and put this white substance from the zinc into it, look how<br \/>\n  beautifully it glows, and just because it is a solid substance.<\/P><br \/>\n  <P>I will now take such a flame as I had a moment since, and set free from it<br \/>\n  the particles of carbon. Here is some camphene, which will burn with a smoke;<br \/>\n  but if I send these particles of smoke through this pipe into the hydrogen<br \/>\n  flame you will see they will burn and become luminous, because we heat them a<br \/>\n  second time. There they are. Those are the particles of carbon reignited a<br \/>\n  second time. They are those particles which you can easily see by holding a<br \/>\n  piece of paper behind them, and which, while they are in the flame, are<br \/>\n  ignited by the heat produced, and, when so ignited, produce this brightness.<br \/>\n  When the particles are not separated you get no brightness. The flame of coal<br \/>\n  gas owes its brightness to the separation, during combustion, of these<br \/>\n  particles of carbon, which are equally in that as in a candle. I can very<br \/>\n  quickly alter that arrangement. Here, for instance is a bright flame of gas.<br \/>\n  Supposing I add so much air to the flame as to cause it all to burn before<br \/>\n  those particles are set free, I shall not have this brightness; and I can do<br \/>\n  that in this way: If I place over the jet this wire-gauze cap, as you see, and<br \/>\n  then light the gas over it, it burns with a non-luminous flame, owing to its<br \/>\n  having plenty of air mixed with it before it burns; and if I raise the gauze,<br \/>\n  you see it does not burn below <SUP>10<\/SUP>. There is plenty of carbon in the<br \/>\n  gas; but, because the atmosphere can get to it, and mix with it before it<br \/>\n  burns, you see how pale and blue the flame is. And if I blow upon a bright gas<br \/>\n  flame, so as to consume all this carbon before it gets heated to the glowing<br \/>\n  point, it will also burn blue. [The lecturer illustrated his remarks by<br \/>\n  blowing on the gas light.] The only reason why I have not the same bright<br \/>\n  light when I thus blow upon the flame is that the carbon meets with sufficient<br \/>\n  air to burn it before it gets separated in the flame in a free state. The<br \/>\n  difference is solely due to the solid particles not being separated before the<br \/>\n  gas is burnt.<\/P><br \/>\n  <BLOCKQUOTE><br \/>\n    <P>[Footnote 10: The &#8220;air-burner,&#8221; which is of such value in the laboratory,<br \/>\n    owes its advantage to this principle. It consists of a cylindrical metal<br \/>\n    chimney, covered at the top with a piece of rather coarse iron wire gauze.<br \/>\n    This is supported over an Argand burner in such a manner that the gas may<br \/>\n    mix in the chimney with an amount of air sufficient to burn the carbon and<br \/>\n    hydrogen simultaneously, so that there may be no separation of carbon in the<br \/>\n    flame with consequent deposition of soot. The flame, being unable to pass<br \/>\n    through the wire gauze, burns in a steady, nearly invisible manner<br \/>\n    above.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>You observe that there are certain products as the result of the combustion<br \/>\n  of a candle, and that of these products one portion may be considered as<br \/>\n  charcoal, or soot; that charcoal, when afterward burnt, produces some other<br \/>\n  product; and it concerns us very much now to ascertain what that other product<br \/>\n  is. We showed that something was going away; and I want you now to understand<br \/>\n  how much is going up into the air; and for that purpose we will have<br \/>\n  combustion on a little larger scale. From that candle ascends heated air, and<br \/>\n  two or three experiments will show you the ascending current; but, in order to<br \/>\n  give you a notion of the quantity of matter which ascends in this way, I will<br \/>\n  make an experiment by which I shall try to imprison some of the products of<br \/>\n  this combustion. For this purpose I have here what boys call a fire-balloon; I<br \/>\n  use this fire-balloon merely as a sort of measure of the result of the<br \/>\n  combustion we are considering; and I am about to make a flame in such an easy<br \/>\n  and simple manner as shall best serve my present purpose. This plate shall be<br \/>\n  the &#8220;cup,&#8221; we will so say, of the candle; this spirit shall be our fuel; and I<br \/>\n  am about to place this chimney over it, because it is better for me to do so<br \/>\n  than to let things proceed at random. Mr. Anderson will now light the fuel,<br \/>\n  and here at the top we shall get the results of the combustion. What we get at<br \/>\n  the top of that tube is exactly the same, generally speaking, as you get from<br \/>\n  the combustion of a candle; but we do not get a luminous flame here, because<br \/>\n  we use a substance which is feeble in carbon. I am about to put this balloon &#8211;<br \/>\n  not into action, because that is not my object &#8211; but to show you the effect<br \/>\n  which results from the action of those products which arise from the candle,<br \/>\n  as they arise here from the furnace. [The balloon was held over the chimney,<br \/>\n  when it immediately commenced to fill.] You see how it is disposed to ascend;<br \/>\n  but we must not let it up; because it might come in contact with those upper<br \/>\n  gaslights, and that would be very inconvenient. [The upper gaslights were<br \/>\n  turned out at the request of the lecturer, and the balloon was allowed to<br \/>\n  ascend.] Does not that show you what a large bulk of matter is being evolved?<br \/>\n  Now there is going through this tube [placing a large glass tube over a<br \/>\n  candle] all the products of that candle, and you will presently see that the<br \/>\n  tube will become quite opaque. Suppose I take another candle, and place it<br \/>\n  under a jar, and then put a light on the other side, just to show you what is<br \/>\n  going on. You see that the sides of the jar become cloudy, and the light<br \/>\n  begins to burn feebly. It is the products, you see, which make the light so<br \/>\n  dim, and this is the same thing which makes the sides of the jar so opaque. If<br \/>\n  you go home, and take a spoon that has been in the cold air, and hold it over<br \/>\n  a candle &#8211; not so as to soot it &#8211; you will find that it becomes dim just as<br \/>\n  that jar is dim. If you can get a silver dish, or something of that kind, you<br \/>\n  will make the experiment still better; and now, just to carry your thoughts<br \/>\n  forward to the time we shall next meet, let me tell you that it is water which<br \/>\n  causes the dimness, and when we next meet I will show that we can make it,<br \/>\n  without difficulty, assume the form of a liquid.<\/P><br \/>\n  <P><STRONG><BR><A name=\"Lecture III\">Lecture III<\/A>: Products:<br \/>\n  Water From The Combustion &#8211; Nature Of Water &#8211; A Compound &#8211;<br \/>\n  Hydrogen<\/STRONG><\/P><\/p>\n<p>  <P>I Dare say you well remember that when we parted we had just mentioned the<br \/>\n  word &#8220;products&#8221; from the candle; for when a candle burns we found we were<br \/>\n  able, by nice adjustment, to get various products from it. There was one<br \/>\n  substance which was not obtained when the candle was burning properly, which<br \/>\n  was charcoal or smoke, and there was some other substance that went upward<br \/>\n  from the flame which did not appear as smoke, but took some other form, and<br \/>\n  made part of that general current which, ascending from the candle upward,<br \/>\n  becomes invisible, and escapes. There were also other products to mention. You<br \/>\n  remember that in that rising current having its origin at the candle we found<br \/>\n  that one part was condensable against a cold spoon, or against a clean plate,<br \/>\n  or any other cold thing, and another part was incondensable.<\/P><br \/>\n  <P>We will first take the condensable part, and examine it, and, strange to<br \/>\n  say, we find that that part of the product is just water &#8211; nothing but water.<br \/>\n  On the last occasion I spoke of it incidentally, merely saying that water was<br \/>\n  produced among the condensable products of the candle; but to-day I wish to<br \/>\n  draw your attention to water, that we may examine it carefully, especially in<br \/>\n  relation to this subject, and also with respect to its general existence on<br \/>\n  the surface of the globe.<\/P><br \/>\n  <P>Now, having previously arranged an experiment for the purpose of condensing<br \/>\n  water from the products of the candle, my next point will be to show you this<br \/>\n  water; and perhaps one of the best means that I can adopt for showing its<br \/>\n  presence to so many at once is to exhibit a very visible action of water and<br \/>\n  then to apply that test to what is collected as a drop at the bottom of that<br \/>\n  vessel. I have here a chemical substance, discovered by Sir Humphry Davy,<br \/>\n  which has a very energetic action upon water, which I shall use as a test of<br \/>\n  the presence of water. If I take a little piece of it &#8211; it is called<br \/>\n  potassium, as coming from potash &#8211; if I take a little piece of it, and throw<br \/>\n  it into the basin, you see how it shows the presence of water by lighting up<br \/>\n  and floating about, burning with a violet flame. I am now going to take away<br \/>\n  the candle which has been burning beneath the vessel containing ice and salt,<br \/>\n  and you see a drop of water &#8211; a condensed product of the candle &#8211; hanging from<br \/>\n  the under surface of the dish. I will show you that potassium has the same<br \/>\n  action upon it as upon the water in that basin in the experiment we have just<br \/>\n  tried. See! it takes fire, and burns in just the same manner. I will take<br \/>\n  another drop upon this glass slab, and when I put the potassium on to it, you<br \/>\n  see at once, from its taking fire, that there is water present. Now that water<br \/>\n  was produced by the candle. In the same manner, if I put this spirit lamp<br \/>\n  under that jar, you will soon see the latter become damp from the dew which is<br \/>\n  deposited upon it &#8211; that dew being the result of combustion; and I have no<br \/>\n  doubt you will shortly see, by the drops of water which fall upon the paper<br \/>\n  below, that there is a good deal of water produced from the combustion of the<br \/>\n  lamp. I will let it remain, and you can afterward see how much water has been<br \/>\n  collected. So, if I take a gas lamp, and put any cooling arrangement over it,<br \/>\n  I shall get water &#8211; water being likewise produced from the combustion of gas.<br \/>\n  Here, in this bottle, is a quantity of water &#8211; perfectly pure, distilled<br \/>\n  water, produced from the combustion of a gas lamp &#8211; in no point different from<br \/>\n  the water that you distill from the river, or ocean, or spring, but exactly<br \/>\n  the same thing. Water is one individual thing; it never changes. We can add to<br \/>\n  it by careful adjustment for a little while, or we can take it apart and get<br \/>\n  other things from it; but water, as water, remains always the same, either in<br \/>\n  a solid, liquid, or fluid state. Here again [holding another bottle] is some<br \/>\n  water produced by the combustion of an oil lamp. A pint of oil, when burnt<br \/>\n  fairly and properly, produces rather more than a pint of water. Here, again,<br \/>\n  is some water, produced by a rather long experiment, from a wax candle. And so<br \/>\n  we can go on with almost all combustible substances, and find that if they<br \/>\n  burn with a flame, as a candle, they produce water. You may make these<br \/>\n  experiments yourselves: the head of a poker is a very good thing to try with,<br \/>\n  and if it remains cold long enough over the candle, you may get water<br \/>\n  condensed in drops on it; or a spoon, or ladle, or any thing else may be used,<br \/>\n  provided it be clean, and can carry off the heat, and so condense the<br \/>\n  water.<\/P><br \/>\n  <P>And now &#8211; to go into the history of this wonderful production of water from<br \/>\n  combustibles, and by combustion &#8211; I must first of all tell you that this water<br \/>\n  may exist in different conditions; and although you may now be acquainted with<br \/>\n  all its forms, they still require us to give a little attention to them for<br \/>\n  the present; so that we may perceive how the water, while it goes through its<br \/>\n  Protean changes, is entirely and absolutely the same thing, whether it is<br \/>\n  produced from a candle, by combustion, or from the rivers or ocean.<\/P><br \/>\n  <P>First of all, water, when at the coldest, is ice. Now we philosophers &#8211; I<br \/>\n  hope that I may class you and myself together in this case &#8211; speak of water as<br \/>\n  water, whether it be in its solid, or liquid, or gaseous state &#8211; we speak of<br \/>\n  it chemically as water. Water is a thing compounded of two substances, one of<br \/>\n  which we have derived from the candle, and the other we shall find elsewhere.<br \/>\n  Water may occur as ice; and you have had most excellent opportunities lately<br \/>\n  of seeing this. Ice changes back into water &#8211; for we had on our last Sabbath a<br \/>\n  strong instance of this change by the sad catastrophe which occurred in our<br \/>\n  own house, as well as in the houses of many of our friends &#8211; ice changes back<br \/>\n  into water when the temperature is raised; water also changes into steam when<br \/>\n  it is warmed enough. The water which we have here before us is in its densest<br \/>\n  state <SUP>11<\/SUP>; and, although it changes in weight, in condition, in<br \/>\n  form, and in many other qualities, it still is water; and whether we alter it<br \/>\n  into ice by cooling, or whether we change it into steam by heat, it increases<br \/>\n  in volume in the one case very strangely and powerfully, and in the other case<br \/>\n  very largely and wonderfully. For instance, I will now take this tin cylinder,<br \/>\n  and pour a little water into it, and, seeing how much water I pour in, you may<br \/>\n  easily estimate for yourselves how high it will rise in the vessel: it will<br \/>\n  cover the bottom about two inches. I am now about to convert the water into<br \/>\n  steam for the purpose of showing to you the different volumes which water<br \/>\n  occupies in its different states of water and steam.<\/P><\/p>\n<p>  <BLOCKQUOTE><br \/>\n    <P>[Footnote 11: Water is in its densest state at a temperature of 39.1<br \/>\n    Fahrenheit.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>Let us now take the case of water changing into ice: we can effect that by<br \/>\n  cooling it in a mixture of salt and pounded ice <SUP>12<\/SUP> &#8211; and I shall do<br \/>\n  so to show you to the expansion of water into a thing of larger bulk when it<br \/>\n  is so changed. These bottles [holding one] are made strong cast iron, very<br \/>\n  strong and very thick &#8211; I suppose they are the third of an inch in thickness;<br \/>\n  they are very carefully filled with water, so as to exclude all air, and then<br \/>\n  they are screwed down tight. We shall see that when we freeze the water in<br \/>\n  these iron vessels, they will not be able to hold the ice, and the expansion<br \/>\n  within them will break them in pieces as these [pointing to some fragments]<br \/>\n  are broken, which have been bottles of exactly the same kind. I am about to<br \/>\n  put these two bottles into that mixture of ice and salt for the purpose of<br \/>\n  showing that when water becomes ice it changes in volume in this extraordinary<br \/>\n  way.<\/P><br \/>\n  <BLOCKQUOTE><br \/>\n    <P>[Footnote 12: A mixture of salt and pounded ice reduces the temperature<br \/>\n    from 32 Fahrenheit to zero, the ice at the same time becoming<br \/>\n  fluid.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>In the mean time, look at the change which has taken place in the water to<br \/>\n  which we have applied heat; it is losing its fluid state. You may tell this by<br \/>\n  two or three circumstances. I have covered the mouth of this glass flask, in<br \/>\n  which water is boiling, with a watch-glass. Do you see what happens? It<br \/>\n  rattles away like a valve chattering, because the steam rising from the<br \/>\n  boiling water sends the valve up and down, and forces itself out, and so makes<br \/>\n  it clatter. You can very easily perceive that the flask is quite full of<br \/>\n  steam, or else it would not force its way out. You see, also, that the flask<br \/>\n  contains a substance very much larger than the water, for it fills the whole<br \/>\n  of the flask over and over again, and there it is blowing away into the air;<br \/>\n  and yet you can not observe any great diminution in the bulk of the water,<br \/>\n  which shows you that its change of bulk is very great when it becomes<br \/>\n  steam.<\/P><\/p>\n<p>  <P>I have put our iron bottles containing water into this freezing mixture,<br \/>\n  that you may see what happens. No communication will take place, you observe,<br \/>\n  between the water in the bottles and the ice in the outer vessel. But there<br \/>\n  will be a conveyance of heat from the one to the other, and if we are<br \/>\n  successful &#8211; we are making our experiment in very great haste &#8211; I expect you<br \/>\n  will by-and-by, so soon as the cold has taken possession of the bottles and<br \/>\n  their contents, hear a pop on the occasion of the bursting of the one bottle<br \/>\n  or the other, and, when we come to examine the bottles, we shall find their<br \/>\n  contents masses of ice, partly inclosed by the covering of iron which is too<br \/>\n  small for them, because the ice is larger in bulk than the water. You know<br \/>\n  very well that ice floats upon water; if a boy falls through a hole into the<br \/>\n  water, he tries to get on the ice again to float him up. Why does the ice<br \/>\n  float? Think of that, and philosophize. Because the ice is larger than the<br \/>\n  quantity of water which can produce it, and therefore the ice weighs the<br \/>\n  lighter and the water is the heavier.<\/P><br \/>\n  <P>To return now to the action of heat on water. See what a stream of vapor is<br \/>\n  issuing from this tin vessel! You observe, we must have made it quite full of<br \/>\n  steam to have it sent out in that great quantity. And now, as we can convert<br \/>\n  the water into steam by heat, we convert it back into liqui! water by the<br \/>\n  application of cold. And if we take a glass, or any other cold thing, and hold<br \/>\n  it over this steam, see how soon it gets damp with water: it will condense it<br \/>\n  until the glass is warm &#8211; it condenses the water which is now running down the<br \/>\n  sides of it. I have here another experiment to show the condensation of water<br \/>\n  from a vaporous state back into a liquid state, in the same way as the vapor,<br \/>\n  one of the products of the candle, was condensed against the bottom of the<br \/>\n  dish and obtained in the form of water; and to show you how truly and<br \/>\n  thoroughly these changes take place, I will take this tin flask, which is now<br \/>\n  full of steam, and close the top. We shall see what takes place when we cause<br \/>\n  this water or steam to return back to the fluid state by pouring some cold<br \/>\n  water on the outside. [The lecturer poured the cold water over the vessel,<br \/>\n  when it immediately collapsed.] You see what has happened. If I had closed the<br \/>\n  stopper, and still kept the heat applied to it, it would have burst the<br \/>\n  vessel; yet, when the steam returns to the state of water, the vessel<br \/>\n  collapses, there being a vacuum produced inside by the condensation of the<br \/>\n  steam. I show you these experiments for the purpose of pointing out that in<br \/>\n  all these occurrences there is nothing that changes the water into any other<br \/>\n  thing; it still remains water; and so the vessel is obliged to give way, and<br \/>\n  is crushed inward, as in the other case, by the farther application of heat,<br \/>\n  it would have been blown outward.<\/P><br \/>\n  <P>And what do you think the bulk of that water is when it assumes the<br \/>\n  vaporous condition? You see that cube [pointing to a cubic foot]. There, by<br \/>\n  its side, is a cubic inch, exactly the same shape as the cubic foot, and that<br \/>\n  bulk of water [the cubic inch] is sufficient to expand into that bulk [the<br \/>\n  cubic foot] of steam; and, on the contrary, the application of cold will<br \/>\n  contract that large quantity of steam into this small quantity of water. [One<br \/>\n  of the iron bottles burst at that moment.] Ah! There is one of our bottles<br \/>\n  burst, and here, you see, is a crack down one side an eighth of an inch in<br \/>\n  width. [The other now exploded, sending the freezing mixture in all<br \/>\n  directions.] This other bottle is also broken; although the iron was nearly<br \/>\n  half an inch thick, the ice has burst it asunder. These changes always take<br \/>\n  place in water; they do not require to be always produced by artificial means;<br \/>\n  we only use them here because we want to produce a small winter round that<br \/>\n  little bottle instead of a long and severe one. But if you go to Canada, or to<br \/>\n  the North, you will find the temperature there out of doors will do the same<br \/>\n  thing as has been done here by the freezing mixture.<\/P><br \/>\n  <P>To return to our quiet philosophy. We shall not in future be deceived,<br \/>\n  therefore, by any changes that are produced in water. Water is the same every<br \/>\n  where, whether produced from the ocean or from the flame of the candle. Where,<br \/>\n  then, is this water which we get from a candle? I must anticipate a little,<br \/>\n  and tell you. It evidently comes, as to part of it, from the candle, but is it<br \/>\n  within the candle beforehand? No, it is not in the candle; and it is not in<br \/>\n  the air around about the candle which is necessary for its combustion. It is<br \/>\n  neither in one nor the other, but it comes from their conjoint action, a part<br \/>\n  from the candle, a part from the air; and this we have now to trace, so that<br \/>\n  we may understand thoroughly what is the chemical history of a candle when we<br \/>\n  have it burning on our table. How shall we get at this? I myself know plenty<br \/>\n  of ways, but I want you to get at it from the association in your own minds of<br \/>\n  what I have already told you.<\/P><br \/>\n  <P>I think you can see a little in this way. We had just now the case of a<br \/>\n  substance which acted upon the water in the way that Sir Humphry Davy showed<br \/>\n  us <SUP>13<\/SUP>, and which I am now going to recall to your minds by making<br \/>\n  again an experiment upon that dish. It is a thing which we have to handle very<br \/>\n  carefully; for you see, if I allow a little splash of water to come upon this<br \/>\n  mass, it sets fire to part of it; and if there were free access of air, it<br \/>\n  would quickly set fire to the whole. Now this is a metal &#8211; a beautiful and<br \/>\n  bright metal &#8211; which rapidly changes in the air, and, as you know, rapidly<br \/>\n  changes in water. I will put a piece on the water, and you see it burns<br \/>\n  beautifully, making a floating lamp, using the water in the place of air.<br \/>\n  Again, if we take a few iron filings or turnings and put them in water, we<br \/>\n  find that they likewise undergo an alteration. They do not change so much as<br \/>\n  this potassium does, but they change somewhat in the same way; they become<br \/>\n  rusty, and show an action upon the water, though in a different degree of<br \/>\n  intensity to what this beautiful metal does; but they act upon the water in<br \/>\n  the same manner generally as this potassium. I want you to put these different<br \/>\n  facts together in your minds. I have another metal here [zinc], and when we<br \/>\n  examined it with regard to the solid substance produced by its combustion, we<br \/>\n  had an opportunity of seeing that it burned; and I suppose, if I take a little<br \/>\n  strip of this zinc and put it over the candle, you will see something half<br \/>\n  way, as it were, between the combustion of potassium on the water and the<br \/>\n  action of iron &#8211; you see there is a sort of combustion. It has burned, leaving<br \/>\n  a white ash or residuum; and here also we find that the metal has a certain<br \/>\n  amount of action upon water.<\/P><\/p>\n<p>  <BLOCKQUOTE><br \/>\n    <P>[Footnote 13: Potassium, the metallic basis of potash, was discovered by<br \/>\n    Sir Humphry Davy in 1807, who succeeded in separating it from potash by<br \/>\n    means of a powerful voltaic battery. Its great affinity for oxygen causes it<br \/>\n    to decompose water with evolution of hydrogen, which takes fire with the<br \/>\n    heat produced.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>By degrees we have learned how to modify the action of these different<br \/>\n  substances, and to make them tell us what we want to know. And now, first of<br \/>\n  all, I take iron. It is a common thing in all chemical reactions, where we get<br \/>\n  any result of this kind, to find that it is increased by the action of heat;<br \/>\n  and if we want to examine minutely and carefully the action of bodies one upon<br \/>\n  another, we often have to refer to the action of heat. You are aware, I<br \/>\n  believe, that iron filings burn beautifully in the air; but I am about to show<br \/>\n  you an experiment of this kind, because it will impress upon you what I am<br \/>\n  going to say about iron in its action on water. If I take a flame and make it<br \/>\n  hollow &#8211; you know why, because I want to get air to it and into it, and<br \/>\n  therefore I make it hollow &#8211; and then take a few iron filings and drop them<br \/>\n  into the flame, you see how well they burn. That combustion results from the<br \/>\n  chemical action which is going on when we ignite those particles. And so we<br \/>\n  proceed to consider these different effects, and ascertain what iron will do<br \/>\n  when it meets with water. It will tell us the story so beautifully, so<br \/>\n  gradually and regularly, that I think it will please you very much.<\/P><br \/>\n  <P>I have here a furnace with a pipe going through it like an iron gun barrel,<br \/>\n  and I have stuffed that barrel full of bright iron turnings, and placed it<br \/>\n  across the fire to be made red-hot. We can either send air through the barrel<br \/>\n  to come in contact with the iron, or we can send steam from this little boiler<br \/>\n  at the end of the barrel. Here is a stop-cock which shuts off the steam from<br \/>\n  the barrel until we wish to admit it. There is some water in these glass jars,<br \/>\n  which I have colored blue, so that you may see what happens. Now you know very<br \/>\n  well that any steam I might send through that barrel, if it went through into<br \/>\n  the water, would be condensed; for you have seen that steam can not retain its<br \/>\n  gaseous form if it be cooled down; you saw it here [pointing to the tin flask]<br \/>\n  crushing itself into a small bulk, and causing the flask holding it to<br \/>\n  collapse; so that if I were to send steam through that barrel it would be<br \/>\n  condensed, supposing the barrel were cold; it is, therefore, heated to perform<br \/>\n  the experiment I am now about to show you. I am going to send the steam<br \/>\n  through the barrel in small quantities, and you shall judge for yourselves,<br \/>\n  when you see it issue from the other end, whether it still remains steam.<br \/>\n  Steam is condensible into water, and when you lower the temperature of steam<br \/>\n  you convert it back into fluid water; but I have lowered the temperature of<br \/>\n  the gas which I have collected in this jar by passing it through water after<br \/>\n  it has traversed the iron barrel, and still it does not change back into<br \/>\n  water. I will take another test and apply to this gas. (I hold the jar in an<br \/>\n  inverted position, or my substance would escape.) If I now apply a light to<br \/>\n  the mouth of the jar, it ignites with a slight noise. That tells you that it<br \/>\n  is not steam; steam puts out a fire; it does not burn; but you saw that what I<br \/>\n  had in that jar burnt. We may obtain this substance equally from water<br \/>\n  produced from the candle flame as from any other source. When it is obtained<br \/>\n  by the action of the iron upon the aqueous vapor, it leaves the iron in a<br \/>\n  state very similar to that in which these filings were after they were burnt.<br \/>\n  It makes the iron heavier than it was before. So long as the iron remains in<br \/>\n  the tube and is heated, and is cooled again without the access of air or<br \/>\n  water, it does not change in its weight; but after having had this current of<br \/>\n  steam passed over it, it then comes out heavier than it was before, having<br \/>\n  taken something out of the steam, and having allowed something else to pass<br \/>\n  forth, which we see here. And now, as we have another jar full, I will show<br \/>\n  you something most interesting. It is a combustible gas; and I might at once<br \/>\n  take this jar and set fire to the contents, and show you that it is<br \/>\n  combustible; but I intend to show you more, if I can. It is also a very light<br \/>\n  substance. Steam will condense; this body will rise in the air, and not<br \/>\n  condense. Suppose I take another glass jar, empty of all but air: if I examine<br \/>\n  it with a taper I shall find that it contains nothing but air. I will now take<br \/>\n  this jar full of the gas that I am speaking of, and deal with it as though it<br \/>\n  were a light body; I will hold both upside down, and turn the one up under the<br \/>\n  other; and that which did contain the gas procured from the steam, what does<br \/>\n  it contain now? You will find it now only contains air. But look! Here is the<br \/>\n  combustible substance [taking the other jar] which I have poured out of the<br \/>\n  one jar into the other. It still preserves its quality, and condition, and<br \/>\n  independence, and therefore is the more worthy of our consideration, as<br \/>\n  belonging to the products of a candle.<\/P><br \/>\n  <P>Now this substance which we have just prepared by the action of iron on the<br \/>\n  steam or water, we can also get by means of those other things which you have<br \/>\n  already seen act so well upon the water. If I take a piece of potassium, and<br \/>\n  make the necessary arrangements, it will produce this gas; and if, instead, a<br \/>\n  piece of zinc, I find, when I come to examine it very carefully, that the main<br \/>\n  reason why this zinc can not act upon the water continuously as the other<br \/>\n  metal does, is because the result of the action of the water envelops the zinc<br \/>\n  in a kind of protecting coat. We have learned in consequence, that if we put<br \/>\n  into our vessel only the zinc and water, they, by themselves, do not give rise<br \/>\n  to much action, and we get no result. But suppose I proceed to dissolve off<br \/>\n  this varnish &#8211; this encumbering substance &#8211; which I can do by a little acid;<br \/>\n  the moment I do this I find the zinc acting upon the water exactly as the iron<br \/>\n  did, but at the common temperature. The acid in no way is altered, except in<br \/>\n  its combination with the oxide of zinc which is produced. I have now poured<br \/>\n  the acid into the glass, and the effect is as though I were applying heat to<br \/>\n  cause this boiling up. There is something coming off from the zinc very<br \/>\n  abundantly, which is not steam. There is a jar full of it; and you will find<br \/>\n  that I have exactly the same combustible substance remaining in the vessel,<br \/>\n  when I hold it upside down, that I produced during the experiment with the<br \/>\n  iron barrel. This is what we get from water, the same substance which is<br \/>\n  contained in the candle.<\/P><br \/>\n  <P>Let us now trace distinctly the connection between these two points. This<br \/>\n  is hydrogen &#8211; a body classed among those things which in chemistry we call<br \/>\n  elements, because we can get nothing else out of them. A candle is not an<br \/>\n  elementary body, because we can get carbon out of it; we can bet this hydrogen<br \/>\n  out of it, or at least out of the water which it supplies. And this gas has<br \/>\n  been so named hydrogen, because it is that element which, in association with<br \/>\n  another generates water. <SUP>14<\/SUP> Mr. Anderson having now been able to<br \/>\n  get two or three jars of gas, we shall have a few experiments to make, and I<br \/>\n  want to show you the best way of making these experiments. I am not afraid to<br \/>\n  show you, for I wish you to make experiments, if you will only make them with<br \/>\n  care and attention, and the assent of those around you. As we advance in<br \/>\n  chemistry we are obliged to deal with substances which are rather injurious if<br \/>\n  in their wrong places; the acids, and heat, and conbustible things we use,<br \/>\n  might do harm if carelessly employed. If you want to make hydrogen, you can<br \/>\n  make it easily from bits of zinc, and sulphuric or pipe into the suds and blow<br \/>\n  bubbles by means of the hydrogen. You observe how the bubbles fall downward<br \/>\n  when I blow them with my warm breath; but notice the difference when I blow<br \/>\n  them with hydrogen. [The lecturer here blew bubbles with hydrogen, which rose<br \/>\n  to the roof of the theatre.] It shows you how light this gas must be in order<br \/>\n  to carry with it not merely the ordinary soap bubble, but the larger portion<br \/>\n  of a drop hanging to the bottom of it. I can show its lightness in a better<br \/>\n  way than this; larger bubbles than these may be so lifted up; indeed, in<br \/>\n  former times balloons used to be filled with this gas. Mr. Anderson will<br \/>\n  fasten this tube on to our generator, and we shall have a stream of hydrogen<br \/>\n  here with which we can charge this balloon made of collodion. I need not even<br \/>\n  be very careful to get all air out, for I know the power of this gas to carry<br \/>\n  it up. [Two collodion balloons were inflated and sent up, one being held by a<br \/>\n  string.] Here is another larger one, made of thin membrane, which we will fill<br \/>\n  and allow to ascend; you will see they will all remain floating about until<br \/>\n  the gas escapes.<\/P><\/p>\n<p>  <BLOCKQUOTE><br \/>\n    <P>[Footnote 14: Yowp, &#8220;water,&#8221; and yevvaw, &#8220;I generate.&#8221;]<\/P><\/BLOCKQUOTE><br \/>\n  <P>What, then, are the comparative weights of these substances? I have a table<br \/>\n  here which will show you the proportion which their weights bear to each<br \/>\n  other. I have taken a pint and a cubic foot as the measures, and have placed<br \/>\n  opposite to them the respective figures. A pint measure of this hydrogen<br \/>\n  weighs three-quarters of our smallest weight, a grain, and a cubic foot weighs<br \/>\n  one-twelfth of an ounce; whereas a pint of water weighs 8,750 grains, and a<br \/>\n  cubic foot of water weighs almost 1,000 ounces. You see, therefore, what a<br \/>\n  vast difference there is between the weight of a cubic foot of water and a<br \/>\n  cubic foot of hydrogen.<\/P><br \/>\n  <P>Hydrogen gives rise to no substance that can become solid, either during<br \/>\n  combustion or afterward as a product of its combustion; but when it burns it<br \/>\n  produces water only; and if we take a cold glass and put it over the flame, it<br \/>\n  becomes damp, and you have water produced immediately in appreciable quantity;<br \/>\n  and nothing is produced by its combustion but the same water which you have<br \/>\n  seen the flame of the candle produce. It is important to remember that this<br \/>\n  hydrogen is the only thing in nature which furnishes water as the sole product<br \/>\n  of combustion.<\/P><br \/>\n  <P>And now we must endeavor to find some additional proof of the general<br \/>\n  character and composition of water, and for this purpose I will keep you a<br \/>\n  little longer, so that at our next meeting we may be better prepared for the<br \/>\n  subject. We have the power of arranging the zinc which you have seen acting<br \/>\n  upon the water by the assistance of an acid, in such a manner as to cause all<br \/>\n  the power to be evolved in the place where we require it. I have behind me a<br \/>\n  voltaic pile, and I am just about to show you, at the end of this lecture, its<br \/>\n  character and power, that you may see what we shall have to deal with when<br \/>\n  next we meet. I hold here the extremities of the wires which transport the<br \/>\n  power from behind me, and which I shall cause to act on the water.<\/P><br \/>\n  <P>We have previously seen what a power of combustion is possessed by the<br \/>\n  potassium, or the zinc, or the iron filings; but none of them show such energy<br \/>\n  as this. [The lecturer here made contact between the two terminal wires of the<br \/>\n  battery, when a brilliant flash of light was produced.] This light is, in<br \/>\n  fact, produced by a forty-zinc power of burning; it is a power that I can<br \/>\n  carry about in my hands through these wires at pleasure, although if I applied<br \/>\n  it wrongly to myself, it would destroy me in an instant, for it is a most<br \/>\n  intense thing, and the power you see here put forth while you count five<br \/>\n  [bringing the poles in contact and exhibiting the electric light] is<br \/>\n  equivalent to the power of several thunder-storms, so great is its force<br \/>\n  <SUP>15<\/SUP>. And that you may see what intense energy it has, I will take<br \/>\n  the ends of the wires which convey the power from the battery, and with it I<br \/>\n  dare say I can burn this iron file. Now this is a chemical power, and one<br \/>\n  which, when we next meet, I shall apply to water, and show you what results we<br \/>\n  are able to produce.<\/P><\/p>\n<p>  <BLOCKQUOTE><br \/>\n    <P>[Footnote 15: Professor Faraday has calculated that there is as much<br \/>\n    electricity required to decompose one grain of water as there is in a very<br \/>\n    powerful flash of lightning.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>&nbsp;<\/P><br \/>\n  <P><STRONG><A name=\"Lecture IV\">Lecture IV<\/A>: Hydrogen In The<br \/>\n  Candle &#8211; Burns Into Water &#8211; The Other Part Of Water &#8211;<br \/>\n  Oxygen<\/STRONG><\/P><br \/>\n  <P>I see you are not tired of the candle yet, or I am sure you would not be<br \/>\n  interested in the subject in the way you are. When our candle was burning we<br \/>\n  found it produced water exactly like the water we have around us; and by<br \/>\n  farther examination of this water we found in it that curious body, hydrogen<br \/>\n  that light substance of which there is some in this jar. We afterward saw the<br \/>\n  burning powers of that hydrogen, and that it produced water. And I think I<br \/>\n  introduced to your notice an apparatus which I very briefly said was an<br \/>\n  arrangement of chemical force, or power, or energy, so adjusted as to convey<br \/>\n  its power to us in these wires; and I said I should use that force to pull the<br \/>\n  water to pieces, to see what else there was in the water besides hydrogen;<br \/>\n  because, you remember, when we passed the water through the iron tube, we by<br \/>\n  no means got the weight of water back which we put in in the form of steam,<br \/>\n  though we had a very large quantity of gas evolved. We have now to see what is<br \/>\n  the other substance present. That you may understand the character and use of<br \/>\n  this instrument, let us make an experiment or two. Let us put together, first<br \/>\n  of all, some substances, knowing what they are, and then see what that<br \/>\n  instrument does to them. There is some copper (observe the various changes<br \/>\n  which it can undergo), and here is some nitric acid, and you will find that<br \/>\n  this, being a strong chemical agent, will act very powerfully when I add it to<br \/>\n  the copper. It is now sending forth a beautiful red vapor; but as we do not<br \/>\n  want that vapor, Mr. Anderson will hold it near the chimney for a short time,<br \/>\n  that we may have the use and beauty of the experiment without the annoyance.<br \/>\n  The copper which I have put into the flask will dissolve it: it will change<br \/>\n  the acid and the water into a blue fluid containing copper and other things,<br \/>\n  and I purpose then showing you how this voltaic battery deals with it; and in<br \/>\n  the mean time we will arrange another kind of experiment for you to see what<br \/>\n  power it has. This is a substance which is to us like water &#8211; that is to say,<br \/>\n  it contains bodies which we do not know of as yet, as water contains a body<br \/>\n  which we do not know as yet. Now this solution of a salt <SUP>16<\/SUP> I will<br \/>\n  put upon paper, and spread about, and apply the power of the battery to it,<br \/>\n  and observe what will happen. Three or four important things will happen which<br \/>\n  we shall take advantage of. I place this wetted paper upon a sheet of tin<br \/>\n  foil, which is convenient for keeping all clean, and also for the advantageous<br \/>\n  application of the power; and this solution, you see, is not at all affected<br \/>\n  by being put upon the paper or tin foil, nor by any thing else I have brought<br \/>\n  in contact with it yet, and which, therefore, is free to us to use as regards<br \/>\n  that instrument. But first let us see that our instrument is in order. Here<br \/>\n  are our wires. Let us see whether it is in the state in which it was last<br \/>\n  time. We can soon tell. As yet, when I bring them together, we have no power,<br \/>\n  because the conveyers &#8211; what we call the electrodes &#8211; the passages or ways for<br \/>\n  the electricity &#8211; are stopped; but now Mr. Anderson by that [referring to a<br \/>\n  sudden flash at the ends of the wires] has given me a telegram to say that it<br \/>\n  is ready. Before I begin our experiment I will get Mr. Anderson to break<br \/>\n  contact again at the battery behind me, and we will put a platinum wire across<br \/>\n  to connect the poles, and then if I find I can ignite a pretty good length of<br \/>\n  this wire we shall be safe in our experiment. Now you will see the power. [The<br \/>\n  connection was established, and the intermediate wire became red-hot.] There<br \/>\n  is the power running beautifully through the wire, which I have made thin on<br \/>\n  purpose to show you that we have those powerful forces; and now, having that<br \/>\n  power, we will proceed with it to the examination of water.<\/P><\/p>\n<p>  <P>&nbsp;<\/P><br \/>\n  <BLOCKQUOTE><br \/>\n    <P>[Footnote 16: A solution of acetate of lead submitted to the action of<br \/>\n    the voltaic current yields lead at the negative pole, and brown peroxide of<br \/>\n    lead at the positive pole. A solution of nitrate of silver, under the same<br \/>\n    circumstances, yields silver at the negative pole, and peroxide of silver at<br \/>\n    the positive pole.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>I have here two pieces of platinum, and if I lay them down upon this piece<br \/>\n  of paper [the moistened paper on the tin foil] you will see no action; and if<br \/>\n  I take them up there is no change that you can see, but the arrangement<br \/>\n  remains just as it was before. But, now, see what happens: if I take these two<br \/>\n  poles and put either one or the other of them down separately on the platinum<br \/>\n  plates, they do nothing for me; both are perfectly without action; but if I<br \/>\n  let them both be in contact at the same moment, see what happens [a brown spot<br \/>\n  appeared under each pole of the battery]. Look here at the effect that takes<br \/>\n  place, and see how I have pulled something apart from the white something<br \/>\n  brown; and I have no doubt, if I were to arrange it thus, and were to put one<br \/>\n  of the poles to the tin foil on the other side of the paper &#8211; why, I get such<br \/>\n  a beautiful action upon the paper that I am going to see whether I can not<br \/>\n  write with it &#8211; a telegram, if you please. [The lecturer here traced the word<br \/>\n  &#8220;juvenile&#8221; on the paper with one of the terminal wires.] See there how<br \/>\n  beautifully we can get our results!<\/P><br \/>\n  <P>You see we have here drawn something which we have not known about before<br \/>\n  out of this solution. Let us now take that flask from Mr. Anderson&#8217;s hands,<br \/>\n  and see what we can draw out of that. This, you know, is a liquid which we<br \/>\n  have just made up from copper and nitric acid while our other experiments were<br \/>\n  in hand; and though I am making this experiment very hastily, and may bungle a<br \/>\n  little, yet I prefer to let you see what I do rather than prepare it<br \/>\n  beforehand<\/P><br \/>\n  <P>Now see what happens. These two platinum plates are the two ends (or I will<br \/>\n  make them so immediately) of this apparatus; and I am about to put them in<br \/>\n  contact with that solution, just as we did a moment ago on the paper. It does<br \/>\n  not matter to us whether the solution be on the paper or whether it be in the<br \/>\n  jar, so long as we bring the ends of the apparatus to it. If I put the two<br \/>\n  platinums in by themselves they come out as clean and as white as they go in<br \/>\n  [inserting them into the fluid without connecting them with the battery]; but<br \/>\n  when we take the power and lay that on [the platinums were connected with the<br \/>\n  battery and again dipped into the solution], this, you see [exhibiting one of<br \/>\n  the platinums], is at once turned into copper, as it were; it has become like<br \/>\n  a plate of copper; and that [exhibiting the other piece of platinum] has come<br \/>\n  out quite clean. If I take this coppered piece and change sides, the copper<br \/>\n  will leave the right-hand side and come over to the left side; what was before<br \/>\n  the coppered plate comes out clean, and the plate which was clean comes out<br \/>\n  coated with copper; and thus you see that the same copper we put into this<br \/>\n  solution we can also take out of it by means of this instrument.<\/P><br \/>\n  <P>Putting that solution aside, let us now see what effect this instrument<br \/>\n  will have upon water. Here are two little platinum plates which I intend to<br \/>\n  make the ends of the battery, and this (C) is a little vessel so shaped as to<br \/>\n  enable me to take it to pieces, and show you its construction. In these two<br \/>\n  cups (A and B) I pour mercury, which touches the ends of the wires connected<br \/>\n  with the platinum plates. In the vessel (C) I pour some water containing a<br \/>\n  little acid (but which is put in only for the purpose of facilitating the<br \/>\n  action; it undergoes no change in the process), and connected with the top of<br \/>\n  the vessel is a bent glass tube (D), which may remind you of the pipe which<br \/>\n  was connected with the gun barrel in our furnace experiment, and which now<br \/>\n  passes under the jar (F). I have now adjusted this apparatus, and we will<br \/>\n  proceed to affect the water in some way or other. In the other case I sent the<br \/>\n  water through a tube which was made red-hot; I am now going to pass the<br \/>\n  electricity through the contents of this vessel. Perhaps I may boil the water;<br \/>\n  if I do boil the water, I shall get vessel, which is now quite clear and<br \/>\n  bright, will become dim. There will be no sound, for the vessel is strong<br \/>\n  enough to confine the explosion. [A spark was then passed through the jar,<br \/>\n  when the explosive mixture was ignited.] Did you see that brilliant light? If<br \/>\n  I again screw the vessel on to the jar, and open these stop-cocks, you will<br \/>\n  see that the gas will rise a second time. [The stop-cocks were then opened.]<br \/>\n  Those gases [referring to the gases first collected in the jar, and which had<br \/>\n  just been ignited by the electric spark] have disappeared, as you see; their<br \/>\n  place is vacant, and fresh gas has gone in. Water has been formed from them;<br \/>\n  and if we repeat our operation [repeating the last experiment], I shall have<br \/>\n  another vacancy, as you will see by the water rising. I always have an empty<br \/>\n  vessel after the explosion, because the vapor or gas into which that water has<br \/>\n  been resolved by the battery explodes under the influence of the spark, and<br \/>\n  changes into water; and by-and-by you will see in this upper vessel some drops<br \/>\n  of water trickling down the sides and collecting at the bottom.<\/P><\/p>\n<p>  <P>We are here dealing with water entirely, without reference to the<br \/>\n  atmosphere. The water of the candle had the atmosphere helping to produce it;<br \/>\n  but in this way it can be produced independently of the air. Water, therefore,<br \/>\n  ought to contain that other substance which the candle takes from the air, and<br \/>\n  which, combining with the hydrogen, produces water.<\/P><br \/>\n  <P>Just now you saw that one end of this battery took hold of the copper,<br \/>\n  extracting it from the vessel which contained the blue solution. It was<br \/>\n  effected by this wire; and surely we may say, if the battery has such power<br \/>\n  with a metallic solution which we made and unmade, may we not find that it is<br \/>\n  possible to split asunder the component parts of the water, and put them into<br \/>\n  this place and that place? Suppose I take the poles &#8211; the metallic ends of<br \/>\n  this battery &#8211; and see what will happen with the water in this apparatus,<br \/>\n  where we have separated the two ends far apart. I place one here (at A), and<br \/>\n  the other there (at B); and I have little shelves with holes which I can put<br \/>\n  upon each pole, and so arrange them that whatever escapes from the two ends of<br \/>\n  the battery will appear as separate gases; for you saw that the water did not<br \/>\n  become vaporous, but gaseous. The wires are now in perfect and proper<br \/>\n  connection with the vessel containing the water, and you see the bubbles<br \/>\n  rising; let us collect these bubbles and see what they are. Here is a glass<br \/>\n  cylinder (O); I fill it with water and put it over one end (A) of the pile,<br \/>\n  and I will take another (H), and put it over the other end (B) of the pile.<br \/>\n  And so now we have a double apparatus, with both places delivering gas. Both<br \/>\n  these jars will fill with gas. There they go, that to the right (H) filling<br \/>\n  very rapidly; the one to the left (O) filling not so rapidly; and, though I<br \/>\n  have allowed some bubbles to escape, yet still the action is going on pretty<br \/>\n  regularly; and were it not that one is rather smaller than the other, you<br \/>\n  would see that I should have twice as much in this (H) as I have in that (O).<br \/>\n  Both these gases are colorless; they stand over the water without condensing;<br \/>\n  they are alike in all things &#8211; I mean in all apparent things; and we have here<br \/>\n  an opportunity of examining these bodies and ascertaining what they are. Their<br \/>\n  bulk is large, and we can easily apply experiments to them. I will take this<br \/>\n  jar (H) first, and will ask you to be prepared to recognize hydrogen.<\/P><br \/>\n  <P>Think of all its qualities &#8211; the light gas which stood well in inverted<br \/>\n  vessels, burning with a pale flame at the mouth of the jar, and see whether<br \/>\n  this gas does not satisfy all these conditions. If it be hydrogen it will<br \/>\n  remain here while I hold this jar inverted. [A light was then applied, when<br \/>\n  the hydrogen burnt.] What is there now in the other jar? You know that the two<br \/>\n  together made an explosive mixture. But what can this be which we find as the<br \/>\n  other constituent in water, and which must therefore be that substance which<br \/>\n  made the hydrogen burn? We know that the water we put into the vessel<br \/>\n  consisted of the two things together. We find one of these is hydrogen: what<br \/>\n  must that other be which was in the water before the experiment, and which we<br \/>\n  now have by itself? I am about to put this lighted splinter of wood into the<br \/>\n  gas. The gas itself will not burn, but it will make the splinter of wood burn.<br \/>\n  [The lecturer ignited the end of the wood and introduced it into the jar of<br \/>\n  gas.] See how it invigorates the combustion of the wood, and how it makes it<br \/>\n  burn far better than the air would make it burn; and now you see by itself<br \/>\n  that every other substance which is contained in the water, and which, when<br \/>\n  the water was formed by the burning of the candle, must have been taken from<br \/>\n  the atmosphere. What shall we call it, A, B, or C? Let us call it O &#8211; call it<br \/>\n  &#8220;Oxygen&#8221;; it is a very good, distinct &#8211; sounding name. This, then, is the<br \/>\n  oxygen which was present in the water, forming so large a part of it.<\/P><br \/>\n  <P>We shall now begin to understand more clearly our experiments and<br \/>\n  researches, because when we have examined these things once or twice we shall<br \/>\n  soon see why a candle burns in the air. When we have in this way analyzed the<br \/>\n  water &#8211; that is to say, separated or electrolyzed its parts out of it, we get<br \/>\n  two volumes of hydrogen and one of the body that burns it. And these two are<br \/>\n  represented to us on the following diagram, with their weights also stated;<br \/>\n  and we shall find that the oxygen is a very heavy body by comparison with the<br \/>\n  hydrogen. It is the other element in water.<\/P><br \/>\n  <P>[Table 1]<\/P><br \/>\n  <P>I had better, perhaps, tell you now how we get this oxygen abundantly,<br \/>\n  having shown you how we can separate it from the water. Oxygen, as you will<br \/>\n  immediately imagine, exists in the atmosphere; for how should the candle burn<br \/>\n  to produce water without it? Such a thing would be absolutely impossible, and<br \/>\n  chemically impossible, without oxygen. Can we get it from the air? Well, there<br \/>\n  are some very complicated and difficult processes by which we can get it from<br \/>\n  the air; but we have better processes. There is a substance called the black<br \/>\n  oxide of manganese; it is a very black-looking mineral, but very useful, and<br \/>\n  when made red-hot it gives out oxygen. Here is an iron bottle which has had<br \/>\n  some of this substance put into it, and there is a tube fixed to it, and a<br \/>\n  fire ready made, and Mr. Anderson will put that retort into the fire, for it<br \/>\n  is made of iron, and can stand the heat. Here is a salt called chlorate of<br \/>\n  potassa, which is now made in large quantities for bleaching, and chemical and<br \/>\n  medical uses, and for pyrotechnic and other purposes. I will take some and mix<br \/>\n  it with some of the oxide of manganese (oxide of copper, or oxide of iron<br \/>\n  would do as well); and if I put these together in a retort, far less than a<br \/>\n  red heat is sufficient to evolve this oxygen from the mixture. I am not<br \/>\n  preparing to make much, because we only want sufficient for our experiments;<br \/>\n  only, as you will see immediately, if I use too small a charge, the first<br \/>\n  portion of the gas will be mixed with the air already in the retort, and I<br \/>\n  should be obliged to sacrifice the first portion of the gas because it would<br \/>\n  be so much diluted with air; the first portion must therefore be thrown away.<br \/>\n  You will find in this case that a common spirit lamp is quite sufficient for<br \/>\n  me to get the oxygen, and so we shall have two processes going on for its<br \/>\n  preparation. See how freely the gas is coming over from that small portion of<br \/>\n  the mixture. We will examine it and see what are its properties. Now in this<br \/>\n  way we are producing, as you will observe, a gas just like the one we had in<br \/>\n  the experiment with the battery, transparent, undissolved by water, and<br \/>\n  presenting the ordinary visible properties of the atmosphere. (As this first<br \/>\n  jar contains the air, together with the first portions of the oxygen set free<br \/>\n  during the preparation, we will carry it out of the way, and be prepared to<br \/>\n  make our experiments in a regular, dignified manner.) And inasmuch as that<br \/>\n  power of making wood, wax, or other things burn, was so marked in the oxygen<br \/>\n  we obtained by means of the voltaic battery from water, we may expect to find<br \/>\n  the same property here. We will try it. You see there is the combustion of a<br \/>\n  lighted taper in air, and here is its combustion in this gas [lowering the<br \/>\n  taper into the jar]. See how brightly and how beautifully it burns! You can<br \/>\n  also see more than this: you will perceive it is a heavy gas, while the<br \/>\n  hydrogen would go up like a balloon, or even faster than a balloon, when not<br \/>\n  encumbered with the weight of the envelope. You may easily see that although<br \/>\n  we obtained from water twice as much in volume of the hydrogen as of oxygen,<br \/>\n  it does not follow that we have twice as much in weight, because one is heavy<br \/>\n  and the other a very light gas. We have means of weighing gases or air; but,<br \/>\n  without stopping to explain that, let me just tell you what their respective<br \/>\n  weights are. The weight of a pint of hydrogen is three-quarters of a grain;<br \/>\n  the weight of the same quantity of oxygen is nearly twelve grains. This is a<br \/>\n  very great difference. The weight of a cubic foot of hydrogen is one-twelfth<br \/>\n  of an ounce; and the weight of a cubic foot of oxygen is one ounce and a<br \/>\n  third. And so on we might come to masses of matter which may be weighed in the<br \/>\n  balance, and which we can take account of as to hundred-weights and as to<br \/>\n  tons, as you will see almost immediately.<\/P><\/p>\n<p>  <P>Now, as regards this very property of oxygen supporting combustion, which<br \/>\n  we may compare to air, I will take a piece of candle to show it you in a rough<br \/>\n  way &#8211; and the result will be rough. There is our candle burning in the air:<br \/>\n  how will it burn in oxygen? I have here a jar of this gas, and I am about to<br \/>\n  put it over the candle for you to compare the action of this gas with that of<br \/>\n  the air. Why, look at it; it looks something like the light you saw at the<br \/>\n  poles of the voltaic battery. Think how vigorous that action must be. And yet,<br \/>\n  during all that action, nothing more is produced than what is produced by the<br \/>\n  burning of the candle in air. We have the same production of water, and the<br \/>\n  same phenomena exactly, when we use this gas instead of air, as we have when<br \/>\n  the candle is burnt in air.<\/P><br \/>\n  <P>But now we have got a knowledge of this new substance, we can look at it a<br \/>\n  little more distinctly, in order to satisfy ourselves that we have got a good<br \/>\n  general understanding of this part of the product of a candle. It is wonderful<br \/>\n  how great the supporting powers of this substance are as regards combustion.<br \/>\n  For instance, here is a lamp which, simple though it be, is the original, I<br \/>\n  may say, of a great variety of lamps which are constructed for divers purposes<br \/>\n  &#8211; for lighthouses, microscopic illuminations, and other uses; and if it was<br \/>\n  proposed to make it burn very brightly, you would say, &#8220;If a candle burnt<br \/>\n  better in oxygen, will not a lamp do the same?&#8221; Why, it will do so. Mr.<br \/>\n  Anderson will give me a tube coming from our oxygen reservoir, and I am about<br \/>\n  to apply it to this flame, which I will previously make burn badly on purpose.<br \/>\n  There comes the oxygen: what a combustion that makes! But if I shut it off,<br \/>\n  what becomes of the lamp? [The flow of oxygen was stopped, and the lamp<br \/>\n  relapsed to its former dimness.] It is wonderful how, by means of oxygen, we<br \/>\n  get combustion accelerated. But it does not affect merely the combustion of<br \/>\n  hydrogen, or carbon, or the candle, but it exalts all combustions of the<br \/>\n  common kind. We will take one which relates to iron, for instance, as you have<br \/>\n  already seen iron burn a little in the atmosphere. Here is a jar of oxygen,<br \/>\n  and this is a piece or iron wire; but if it were a bar as thick as my wrist,<br \/>\n  it would burn the same. I first attach a little piece of wood to the iron; I<br \/>\n  then set the wood on fire, and let them both down together into the jar. The<br \/>\n  wood is now alight, and there it burns as wood should burn in oxygen; but it<br \/>\n  will soon communicate its combustion to the iron. The iron is now burning<br \/>\n  brilliantly, and will continue so for a long time. As long as we supply<br \/>\n  oxygen, so long we can carry on the combustion of the iron, until the latter<br \/>\n  is consumed.<\/P><br \/>\n  <P>We will now put that on one side, and take some other substance; but we<br \/>\n  must limit our experiments, for we have not time to spare for all the<br \/>\n  illustrations you would have a right to if we had more time. We will take a<br \/>\n  piece of sulphur: you know how sulphur burns in the air; well, we put it into<br \/>\n  the oxygen, and you will see that whatever can burn in air can burn with a far<br \/>\n  greater intensity in oxygen, leading you to think that perhaps the atmosphere<br \/>\n  itself owes all its power of combustion to this gas. The sulphur is now<br \/>\n  burning very quietly in the oxygen; but you can not for a moment mistake the<br \/>\n  very high and increased action which takes place when it is so burnt, instead<br \/>\n  of being burnt merely in common air.<\/P><br \/>\n  <P>I am now about to show you the combustion of another substance phosphorus.<br \/>\n  I can do it better for you here than you can do it at home. This is a very<br \/>\n  combustible substance; and if it be so combustible in air, what might you<br \/>\n  expect it would be in oxygen? I am about to show it to you not in its fullest<br \/>\n  intensity, for if I did so we should almost blow the apparatus up; I may even<br \/>\n  now crack the jar, though I do not want to break things carelessly. You see<br \/>\n  how it burns in the air. But what a glorious light it gives out when I<br \/>\n  introduce it into oxygen! [Introducing the lighted phosphorus into the jar of<br \/>\n  oxygen.] There you see the solid particles going off which cause the<br \/>\n  combustion to be so brilliantly luminous.<\/P><br \/>\n  <P>Thus far we have tested this power of oxygen, and the high combustion it<br \/>\n  produces, by means of other substances. We must now, for a little while<br \/>\n  longer, look at it as respects the hydrogen. You know, when we allowed the<br \/>\n  oxygen and the hydrogen derived from the water to mix and burn together, we<br \/>\n  had a little explosion. You remember also that when I burnt the oxygen and the<br \/>\n  hydrogen in a jet together, we got very little light, but great heat; I am now<br \/>\n  about to set fire to oxygen and hydrogen mixed in the proportion in which they<br \/>\n  occur in water. Here is a vessel containing one volume of oxygen and two<br \/>\n  volumes of hydrogen. This mixture is exactly of the same nature as the gas we<br \/>\n  just now obtained from the voltaic battery; it would be far too much to burn<br \/>\n  at once; I have therefore arranged to blow soap bubbles with it and burn those<br \/>\n  bubbles, that we may see by a general experiment or two how this oxygen<br \/>\n  supports the combustion of the hydrogen. First of all, we will see whether we<br \/>\n  can blow a bubble. Well, there goes the gas [causing it to issue through a<br \/>\n  tobacco-pipe into some soapsuds]. Here I have a bubble. I am receiving them on<br \/>\n  my hand, and you will perhaps think I am acting oddly in this experiment, but<br \/>\n  it is to show you that we must not always trust to noise and sounds, but<br \/>\n  rather to real facts. [Exploding a bubble on the palm of his hand.] I am<br \/>\n  afraid to fire a bubble from the end of the pipe, because the explosion would<br \/>\n  pass up into the jar and blow it to pieces. This oxygen then, will unite with<br \/>\n  the hydrogen, as you see by the phenomena, and hear by the sound, with the<br \/>\n  utmost readiness of action, and all its powers to then taken up in its<br \/>\n  neutralization of the qualities of the hydrogen.<\/P><br \/>\n  <P>So now I think you will perceive the whole history of water with reference<br \/>\n  to oxygen and the air from what we have before said. Why does a piece of<br \/>\n  potassium decompose water? Because it finds oxygen in the water. What is set<br \/>\n  free when I put it in the water, as I am about to do again? It sets free<br \/>\n  hydrogen, and the hydrogen burns; but the potassium itself combines with<br \/>\n  oxygen; and this piece of potassium, in taking the water apart &#8211; the water,<br \/>\n  you may say, derived from the combustion of the candle &#8211; takes away the oxygen<br \/>\n  which the candle took from the air, and so sets the hydrogen free; and even if<br \/>\n  I take a piece of ice, and put a piece of potassium upon it, the beautiful<br \/>\n  affinities by which the oxygen and the hydrogen are related are such that the<br \/>\n  ice will absolutely set fire to the potassium. I show this to you to-day, in<br \/>\n  order to enlarge your ideas of these things, and that you may see how greatly<br \/>\n  results are modified by circumstances. There is the potassium on the ice,<br \/>\n  producing a sort of volcanic action.<\/P><\/p>\n<p>  <P>It will be my place when next we meet, having pointed out these anomalous<br \/>\n  actions, to show you that none of these extra and strange effects are met with<br \/>\n  by us &#8211; that none of these strange and injurious actions take place when we<br \/>\n  are burning, not merely a candle, but gas in our streets, or fuel in our<br \/>\n  fireplaces, so long as we confine ourselves within the laws that Nature has<br \/>\n  made for our guidance.<\/P><br \/>\n  <P>&nbsp;<\/P><br \/>\n  <P><STRONG><A name=\"Lecture V\">Lecture V<\/A>: Oxygen Present In The<br \/>\n  Air &#8211; Nature Of The Atmosphere &#8211; Carbonic Acid<\/STRONG><\/P><br \/>\n  <P>We have now seen that we can produce hydrogen and oxygen from the water<br \/>\n  that we obtained from the candle. Hydrogen, you know, comes from the candle,<br \/>\n  and oxygen, you believe, comes from the air. But then you have a right to ask<br \/>\n  me, &#8220;How is it that the air and the oxygen do not equally well burn the<br \/>\n  candle?&#8221; If you remember what happened when I put a jar of oxygen over a piece<br \/>\n  of candle, you recollect there was a very different kind of combustion to that<br \/>\n  which took place in the air. Now, why is this? It is a very important<br \/>\n  question, and one I shall endeavor to make you understand; it relates most<br \/>\n  intimately to the nature of the atmosphere, and is most important to us.<\/P><br \/>\n  <P>We have several tests for oxygen besides the mere burning of bodies; you<br \/>\n  have seen a candle burnt in oxygen or in the air; you have seen phosphorus<br \/>\n  burnt in the air or in oxygen, and you have seen iron filings burnt in oxygen.<br \/>\n  But we have other tests besides these, and I am about to refer to one or two<br \/>\n  of them for the purpose of carrying your conviction and your experience<br \/>\n  farther. Here we have a vessel of oxygen. I will show its presence to you: If<br \/>\n  I take a little spark and put it into that oxygen, you know by the experience<br \/>\n  you gained the last time we met what will happen &#8211; if I put that spark into<br \/>\n  the jar, it will tell you whether we have oxygen here or not. Yes! We have<br \/>\n  proved it by combustion; and now here is another test for oxygen, which is a<br \/>\n  very curious and useful one. I have here two jars full of gas, with a plate<br \/>\n  between them to prevent their mixing; I take the plate away, and the gases are<br \/>\n  creeping one into the other. &#8220;What happens?&#8221; say you; &#8220;they together produce<br \/>\n  no such combustion as was seen in the case of the candle.&#8221; But see how the<br \/>\n  presence of oxygen is told by its association with this other substance.<br \/>\n  <SUP>17<\/SUP> What a beautifully colored gas I have obtained in this way,<br \/>\n  showing me the presence of the oxygen! In the same way we can try this<br \/>\n  experiment by mixing common air with this test-gas. Here is a jar containing<br \/>\n  air-such air as the candle would burn in &#8211; and here is a jar or bottle<br \/>\n  containing the test &#8211; gas. I let them come together over water, and you see<br \/>\n  the result: the contents of the test-bottle are flowing into the jar of air,<br \/>\n  and you see I obtain exactly the same kind of action as before, and that shows<br \/>\n  me that there is oxygen in the air &#8211; the very same substance that has been<br \/>\n  already obtained by us from the water produced by the candle. But then, beyond<br \/>\n  that, how is it that the candle does not burn in air as well as in oxygen? We<br \/>\n  will come to that point at once. I have here two jars; they are filled to the<br \/>\n  same height with gas, and the appearance to the eye is alike in both, and I<br \/>\n  really do not know at present which of these jars contains oxygen and which<br \/>\n  contains air, although I know they have previously been filled with these<br \/>\n  gases. But here is our test-gas, and I am going to work with the two jars, in<br \/>\n  order to examine whether there is any difference between them in the quality<br \/>\n  of reddening this gas. I am now going to turn this test-gas into one of the<br \/>\n  jars, and observe what happens. There is reddening, you see; there is, then,<br \/>\n  oxygen present. We will now test the other jar; but you see this is not so<br \/>\n  distinctly red as the first, and, farther, this curious thing happens; if I<br \/>\n  take these two gases and shake them well together with water, we shall absorb<br \/>\n  the red gas; and then, if I put in more of this test-gas and shake again, we<br \/>\n  shall absorb more; and I can go on as long as there be any oxygen present to<br \/>\n  produce that effect. If I let in air, it will not matter; but the moment I<br \/>\n  introduce water, the red gas disappears; and I may go on in this way, putting<br \/>\n  in more and more of the test &#8211; gas, until I come to something left behind<br \/>\n  which will not redden any longer by the use of that particular body that<br \/>\n  rendered the air and the oxygen red. Why is that? You see in a moment it is<br \/>\n  because there is, besides oxygen, something else present which is left behind.<br \/>\n  I will let a little more air into the jar, and if it turns red you will know<br \/>\n  that some of that reddening gas is still present, and that, consequently, it<br \/>\n  was not for the want of this producing body that that air was left behind.<\/P><\/p>\n<p>  <BLOCKQUOTE><br \/>\n    <P>[Footnote 17: The gas which is thus employed as a test for the presence<br \/>\n    of oxygen is the binoxide of nitrogen, or nitrous oxide. It is a colorless<br \/>\n    gas, which, when brought in contact with oxygen, unites with it, forming<br \/>\n    hyponitric acid, the red gas referred to.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>Now you will begin to understand what I am about to say. You saw that when<br \/>\n  I burnt phosphorus in a jar, as the smoke produced by the phosphorus and the<br \/>\n  oxygen of the air condensed, it left a good deal of gas unburnt, just as this<br \/>\n  red gas left something untouched; there was, in fact, this gas left behind,<br \/>\n  which the phosphorus can not touch, which the reddening gas can not touch, and<br \/>\n  this something is not oxygen, and yet is part of the atmosphere.<\/P><br \/>\n  <P>So that is one way of opening out air into the two things of which it is<br \/>\n  composed &#8211; oxygen, which burns our candles, our phosphorus, or any thing else,<br \/>\n  and this other substance &#8211; nitrogen &#8211; which will not burn them. This other<br \/>\n  part of the air is by far the larger proportion, and it is a very curious body<br \/>\n  when we come to examine it; it is remarkably curious, and yet you say,<br \/>\n  perhaps, that it is very uninteresting. It is uninteresting in some respects<br \/>\n  because of this, that it shows no brilliant effects of combustion. If I test<br \/>\n  it with a taper as I do oxygen and hydrogen, it does not burn like hydrogen,<br \/>\n  nor does it make the taper burn like oxygen. Try it in any way I will, it does<br \/>\n  neither the one thing nor the other; it will not take fire; it will not let<br \/>\n  the taper burn; it puts out the combustion of every thing. There is nothing<br \/>\n  that will burn in it in common circumstances. It has no smell; it is not sour;<br \/>\n  it does not dissolve in water; it is neither an acid nor an alkali; it is as<br \/>\n  indifferent to all our organs as it is possible for a thing to be. And you<br \/>\n  might say, &#8220;It is nothing; it is not worth chemical attention; what does it do<br \/>\n  in the air?&#8221; Ah! then come our beautiful and fine results shown us by an<br \/>\n  observant philosophy. Suppose, in place of having nitrogen, or nitrogen and<br \/>\n  oxygen, we had pure oxygen as our atmosphere; what would become of us? You<br \/>\n  know very well that a piece of iron lit in a jar of oxygen goes on burning to<br \/>\n  the end. When you see a fire in an iron grate, imagine where the grate would<br \/>\n  go to if the whole of the atmosphere were oxygen. The grate would burn up more<br \/>\n  powerfully than the coals; for the iron of the grate itself is even more<br \/>\n  combustible than the coals which we burn in it. A fire put into the middle of<br \/>\n  a locomotive would be a fire in a magazine of fuel, if the atmosphere were<br \/>\n  oxygen. The nitrogen lowers it down and makes it moderate and useful for us,<br \/>\n  and then, with all that, it takes away with it the fumes that you have seen<br \/>\n  produced from the candle, disperses them throughout the whole of the<br \/>\n  atmosphere, and carries them away to places where they are wanted to perform a<br \/>\n  great and glorious purpose of good to man, for the sustenance of vegetation,<br \/>\n  and thus does a most wonderful work, although you say, on examining it, &#8220;Why,<br \/>\n  it is a perfectly indifferent thing.&#8221; This nitrogen in its ordinary state is<br \/>\n  an inactive element; no action short of the most intense electric force, and<br \/>\n  then in the most infinitely small degree, can cause the nitrogen to combine<br \/>\n  directly with the other element of the atmosphere, or with other things round<br \/>\n  about it; it is a perfectly indifferent, and therefore to say, a safe<br \/>\n  substance.<\/P><br \/>\n  <P>But, before I take you to that result, I must tell you about the atmosphere<br \/>\n  itself. I have written on this diagram the composition of one hundred parts of<br \/>\n  atmospheric air:<\/P><br \/>\n  <P>&#8212;Table 2]<\/P><\/p>\n<p>  <P>It is a true analysis of the atmosphere so far as regards the quantity of<br \/>\n  oxygen and the quantity of nitrogen present. By our analysis, we find that 5<br \/>\n  pints of the atmosphere contain only 1 pint of oxygen, and 4 pints, or 4<br \/>\n  parts, of nitrogen by bulk. That is our analysis of the atmosphere. It<br \/>\n  requires all that quantity of nitrogen to reduce the oxygen down, so as to be<br \/>\n  able to supply the candle properly with fuel, so as to supply us with an<br \/>\n  atmosphere which our lungs can healthily and safely breathe; for it is just as<br \/>\n  important to make the oxygen right for us to breathe, as it is to make the<br \/>\n  atmosphere right for the burning of the fire and the candle.<\/P><br \/>\n  <P>But now for this atmosphere. First of all, let me tell you the weight of<br \/>\n  these gases. A pint of nitrogen weighs 10 4-10 grains, or a cubic foot weighs<br \/>\n  1 1-6 ounces. That is the weight of the nitrogen. The oxygen is heavier: a<br \/>\n  pint of it weighs 11 9-10 grs., and a cubic foot weighs 1 3-4 oz. A pint of<br \/>\n  air weighs about 10 7-10 grs., and a cubic foot 1 1-5 oz.<\/P><br \/>\n  <P>You have asked me several times, and I am very glad you have, &#8220;How do you<br \/>\n  weigh gases?&#8221; I will show you: it is very simple, and easily done. Here is a<br \/>\n  balance, and here a copper bottle, made as light as we can consistent with due<br \/>\n  strength, turned very nicely in the lathe, and made perfectly air-tight, with<br \/>\n  a stop-cock, which we can open and shut, which at present is open, and,<br \/>\n  therefore, allows the bottle to be full of air. I have here a nicely adjusted<br \/>\n  balance in which I think the bottle, in its present condition, will be<br \/>\n  balanced by the weight on the other side. And here is a pump by which we can<br \/>\n  force the air into this bottle, and with it we will force in a certain number<br \/>\n  of volumes of air as measured by the pump. [Twenty measures were pumped in.]<br \/>\n  We will shut that in and put it in the balance. See how it sinks; it is much<br \/>\n  heavier than it was. By what? By the air that we have forced into it by the<br \/>\n  pump. There is not a greater bulk of air, but there is the same bulk of<br \/>\n  heavier air, because we have forced in air upon it. And that you may have a<br \/>\n  fair notion in your mind as to how much this air measures, here is a jar full<br \/>\n  of water. We will open that copper vessel into this jar, and let the air<br \/>\n  return to its former state. All I have to do now is to screw them tightly<br \/>\n  together, and to turn the taps, when there, you see, is the bulk of the twenty<br \/>\n  pumps of air which I forced into the bottle; and to make sure that we have<br \/>\n  been quite correct in what we have been doing, we will take the bottle again<br \/>\n  to the balance, and, if it is now counterpoised by the original weight, we<br \/>\n  shall be quite sure we have made our experiment correctly. It is balanced; so,<br \/>\n  you see, we can find out the weight of the extra volumes of air forced in that<br \/>\n  way, and by that means we are able to ascertain that a cubic foot of air<br \/>\n  weighs 1 1-5 oz. But that small experiment will by no means convey to your<br \/>\n  mind the whole literal truth of this matter. It is wonderful how it<br \/>\n  accumulates when you come to larger volumes. This bulk of air [a cubic foot]<br \/>\n  weighs 1 1-5 oz. What do you think of the contents of that box above there<br \/>\n  which I have had made for the purpose? The air which is within that box weigh<br \/>\n  one pound &#8211; a full pound; and I have calculated the weight of the air in this<br \/>\n  room: you would hardly imagine it, but it is above a ton. So rapidly do the<br \/>\n  weights rise up, and so important is the presence to the atmosphere, and of<br \/>\n  the oxygen and the nitrogen in it, and the use it performs in conveying things<br \/>\n  to and fro from place to place, and carrying bad vapors to places where they<br \/>\n  will do good instead of harm.<\/P><br \/>\n  <P>Having given you that little illustration with respect to the weight of the<br \/>\n  air, let me show you certain consequences of it. You have a right to them,<br \/>\n  because you would not understand so much without it. Do you remember this kind<br \/>\n  of experiment? Have you ever seen it? Suppose I take a pump somewhat similar<br \/>\n  to the one I had a little while ago to force air into the bottle, and suppose<br \/>\n  I place it in such a manner that by certain arrangements I can apply my hand<br \/>\n  to it. My hand moves about in the air so easily that it seems to feel nothing,<br \/>\n  and I can hardly get velocity enough by any motion of my own in the atmosphere<br \/>\n  to make sure that there is much resistance to it. But when I put my hand here<br \/>\n  [on the air-pump receiver, which was afterward exhausted] you see what<br \/>\n  happens. Why is my hand fastened to this place, and why am I able to pull this<br \/>\n  pump about? And see! how is it that I can hardly get my hand away? Why is<br \/>\n  this? It is the weight of the air &#8211; the weight of the air that is above. I<br \/>\n  have another experiment here, which I think will explain to you more about it.<br \/>\n  When the air is pumped from underneath the bladder which is stretched over<br \/>\n  this glass, you will see the effect in another shape: the top is quite flat at<br \/>\n  present, but I will make a very little motion with the pump, and now look at<br \/>\n  it; see how it has gone down, see how it is bent in; you will see the bladder<br \/>\n  go in more and more, until, at last, I expect it will be driven in and broken<br \/>\n  by the force of the atmosphere pressing upon it. [The bladder at last broke<br \/>\n  with a loud report.] Now that was done entirely by the weight of the air<br \/>\n  pressing on it, and you can easily understand how that is. The particles that<br \/>\n  are piled up in the atmosphere stand upon each other, as these five cubes do;<br \/>\n  you can easily conceive that four of these five cubes are resting upon the<br \/>\n  bottom one, and if I take that away the others will all sink down. So it is<br \/>\n  with the atmosphere; the air that is above is sustained by the air that is<br \/>\n  beneath, and when the air is pumped away from beneath them, the change occurs<br \/>\n  which you saw when I placed my hand on the air-pump, and which you saw in the<br \/>\n  case of the bladder, and which you shall see better here. I have tied over<br \/>\n  this jar a piece of sheet India-rubber, and I am now about to take away the<br \/>\n  air from the inside of the jar; and if you will watch the India-rubber which<br \/>\n  acts as a partition between the air below and the air above &#8211; you will see,<br \/>\n  when I pump, how the pressure shows itself. See where it is going to: I can<br \/>\n  actually put my hand into the jar; and yet this result is only caused by the<br \/>\n  great and powerful action of the air above. How beautifully it shows this<br \/>\n  curious circumstance!<\/P><br \/>\n  <P>Here is something that you can have a pull at when I have finished to day.<br \/>\n  It is a little apparatus of two hollow brass hemispheres, closely fitted<br \/>\n  together, and having connected with it a pipe and a cock, through which we can<br \/>\n  exhaust the air from the inside; and although the two halves are so easily<br \/>\n  taken apart, while the air is left within, yet you will see, when we exhaust<br \/>\n  it by-and-by, no power of any two of you will be able to pull them apart.<br \/>\n  Every square inch of surface that is contained in the area of that vessel<br \/>\n  sustains fifteen pounds by weight, or nearly so, when the air is taken out,<br \/>\n  and you may try your strength presently in seeing whether you can overcome<br \/>\n  that pressure of the atmosphere.<\/P><br \/>\n  <P>Here is another very pretty thing &#8211; the boy&#8217;s sucker, only refined by the<br \/>\n  philosopher. We young ones have a perfect right to take toys and make them<br \/>\n  into philosophy, inasmuch as nowadays we are turning philosophy into toys.<br \/>\n  Here is a sucker, only it is made of India-rubber. If I clap it upon the<br \/>\n  table, you see at once it holds. Why does it hold? I can slip it about, and<br \/>\n  yet if I try to pull it up, it seems as if it would pull the table with it. I<br \/>\n  can easily make it slip about from place to place, but only when I bring it to<br \/>\n  the edge of the table can I get it off. It is only kept down by the pressure<br \/>\n  of the atmosphere above; we have a couple of them, and if you take these two<br \/>\n  and press them together, you will see how firmly they stick. And, indeed, we<br \/>\n  may use them as they are proposed to be used, to stick against windows, or<br \/>\n  against walls, where they will adhere for an evening, and serve to hang any<br \/>\n  thing on that you want. I think, however, that you boys ought to be shown<br \/>\n  experiments that you can make at home; and so here is a very pretty experiment<br \/>\n  in illustration of the pressure of the atmosphere. Here is a tumbler of water.<br \/>\n  Suppose I were to ask you to turn that tumbler upside down so that the water<br \/>\n  should not fall out, and yet not be kept in by your hand, but merely by using<br \/>\n  the pressure of the atmosphere; could you do that? Take a wine-glass, either<br \/>\n  quite full or half full of water, and put a flat card on the top; turn it<br \/>\n  upside down, and then see what becomes of the card and of the water. The air<br \/>\n  can not get in because the water, by its capillary attraction round the edge,<br \/>\n  keeps it out.<\/P><\/p>\n<p>  <P>I think this will give you a correct notion of what you may call the<br \/>\n  materiality of the air; and when I tell you that that box holds a pound of it,<br \/>\n  and this room more than a ton, you will begin to think that air is something<br \/>\n  very serious. I will make another experiment to convince you of this positive<br \/>\n  resistance. There is that beautiful experiment of the popgun, made so well and<br \/>\n  so easily, you know, out of a quill, or a tube, or any thing of that kind,<br \/>\n  where we take a slice of potato, for instance, or an apple, and take the tube<br \/>\n  and cut out a pellet, as I have now done, and push it to one end. I have made<br \/>\n  that end tight; and now I take another piece and put it in: it will confine<br \/>\n  the air that is within the tube perfectly and completely for our purpose; and<br \/>\n  I shall now find it absolutely impossible by any force of mine to drive that<br \/>\n  little pellet close up to the other. It can not be done; I may press the air<br \/>\n  to a certain extent, but if I go on pressing, long before it comes to the<br \/>\n  second, the confined air will drive the front one out with a force something<br \/>\n  like that of gunpowder; for gunpowder is in part dependent upon the same<br \/>\n  action that you see here exemplified.<\/P><br \/>\n  <P>I saw the other day an experiment which pleased me much, as I thought it<br \/>\n  would served our purpose here. (I ought to have held my tongue for four or<br \/>\n  five minutes before beginning this experiment, because it depends upon my<br \/>\n  lungs for success.) By the proper application of air, I expect to be able to<br \/>\n  drive this egg out of one cup into the other by the force of my breath; but if<br \/>\n  I fail it is in a good cause, and I do not promise success, because I have<br \/>\n  been talking more than I ought to do to make the experiment succeed.<\/P><br \/>\n  <P>[The lecturer here tried the experiment, and succeeded in blowing the egg<br \/>\n  from one egg cup to the other.]<\/P><br \/>\n  <P>You see that the air which I blow goes downward between the egg and the<br \/>\n  cup, and makes a blast under the egg, and is thus able to lift a heavy thing;<br \/>\n  for a full egg is a very heavy thing for air to lift. If you want to make the<br \/>\n  experiment, you had better boil the egg quite hard first, and then you may<br \/>\n  very safely try to blow it from one cup to the other, with a little care.<\/P><br \/>\n  <P>I have now kept you long enough upon this property of the weight of the<br \/>\n  air, but there is another thing I should like to mention. You saw the way in<br \/>\n  which, in this popgun, I was able to drive the second piece of potato half or<br \/>\n  two-thirds of an inch before the first piece started, by virtue of the<br \/>\n  elasticity of the air, just as I pressed into the copper bottle the particles<br \/>\n  of air by means of the pump. Now this depends upon a wonderful property in the<br \/>\n  air, namely, its elasticity, and I should like to give you a good illustration<br \/>\n  of this. If I take any thing that confines the air properly, as this membrane,<br \/>\n  which also is able to contract and expand so as to give us a measure of the<br \/>\n  elasticity of the air, and confine in this bladder a certain portion of air;<br \/>\n  and then, if we take the atmosphere off from the outside of it, just as in<br \/>\n  these cases we put the pressure on &#8211; if we take the pressure off, you will see<br \/>\n  how it will then go on expanding and expanding, larger and larger, until it<br \/>\n  will fill the whole of this bell jar, showing you that wonderful property of<br \/>\n  the air, its elasticity, its compressibility, and expansibility, to an<br \/>\n  exceedingly large extent, and which is very essential for the purposes and<br \/>\n  services it performs in the economy of creation.<\/P><br \/>\n  <P>We will now turn to another very important part of our subject, remembering<br \/>\n  that we have examined the candle in its burning, and have found that it gives<br \/>\n  rise to various products. We have the products, you know, of soot, of water,<br \/>\n  and of something else, which you have not yet examined. We have collected the<br \/>\n  water, but have allowed the other things to go into the air. Let us now<br \/>\n  examine some of these other products.<\/P><\/p>\n<p>  <P>Here is an experiment which I think will help you in part in this way. We<br \/>\n  will put our candle there, and place over it a chimney, thus. I think my<br \/>\n  candle will go on burning, because the air passage is open at the bottom and<br \/>\n  the top. In the first place, you see the moisture appearing &#8211; that you know<br \/>\n  about. It is water produced from the candle by the action of the air upon its<br \/>\n  hydrogen. But, besides that, something is going out at the top: it is not<br \/>\n  moisture &#8211; it is not water &#8211; it is not condensible; and yet, after all, it has<br \/>\n  very singular properties. You will find that the air coming out of the top of<br \/>\n  our chimney is nearly sufficient to blow the light out I am holding to it; and<br \/>\n  if I put the light fairly opposed to the current, it will blow it quite out.<br \/>\n  You will say, that is as it should be, and I am supposing that you think it<br \/>\n  ought to do so, because the nitrogen does not support combustion, and ought to<br \/>\n  put the candle out, since the candle will not burn in nitrogen. But is there<br \/>\n  nothing else there than nitrogen? I must now anticipate &#8211; that is to say, I<br \/>\n  must use my own knowledge to supply you with the means that we adopt for the<br \/>\n  purpose of ascertaining these things, and examining such gases as these. I<br \/>\n  will take an empty bottle &#8211; here is one &#8211; and if I hold it over this chimney,<br \/>\n  I shall get the combustion of the candle below sending its results into the<br \/>\n  bottle above; and we shall soon find that this bottle contains, not merely an<br \/>\n  air that is bad as regards the combustion of a taper put into it, but having<br \/>\n  other properties.<\/P><br \/>\n  <P>Let me take a little quick-lime and pour some common water on to it the<br \/>\n  commonest water will do. I will stir it a moment, then pour it upon a piece of<br \/>\n  filtering paper in a funnel, and we shall very quickly have a clear water<br \/>\n  proceeding to the bottle below, as I have here. I have plenty of this water in<br \/>\n  another bottle, but nevertheless I should like to use the lime water that was<br \/>\n  prepared before you, so that you may see what its uses are. If I take some of<br \/>\n  this beautiful clear lime-water, and pour it into this jar which has collected<br \/>\n  the air from the candle, you will see a change coming about. Do you see that<br \/>\n  the water has become quite milky? Observe, that will not happen with air<br \/>\n  merely. Here is a bottle filled with air; and if I put a little lime-water<br \/>\n  into it, neither the oxygen nor the nitrogen, nor any thing else that is in<br \/>\n  that quantity of air, will make any change in the lime water. It remains<br \/>\n  perfectly clear, and no shaking of that quantity of lime water with that<br \/>\n  quantity of air in its common state will cause any change; but if I take this<br \/>\n  bottle with the lime-water and hold it so as to get the general products of<br \/>\n  the candle in contact with it, in a very short time we shall have it milky.<br \/>\n  There is the chalk, consisting of the lime which we used in making the<br \/>\n  lime-water, combined with something that came from the candle &#8211; that other<br \/>\n  product which we are in search of, and which I want to tell you about today.<br \/>\n  This is a substance made visible to us by its action, which is not the action<br \/>\n  of the lime-water either upon the oxygen or upon the nitrogen, nor upon the<br \/>\n  water itself, but it is something new to us from the candle. And then we find<br \/>\n  this white powder, produced by the lime-water and the vapor from the candle,<br \/>\n  appears to us very much like whitening or chalk, and when examined it does<br \/>\n  prove to be exactly the same substance as whitening or chalk. So we are led,<br \/>\n  or have been led, to observe upon the various circumstances of this<br \/>\n  experiment, and to trace this production of chalk to its various causes, to<br \/>\n  give us the true knowledge of the nature of this combustion of the candle &#8211; to<br \/>\n  find that this substance issuing from the candle is exactly the same as that<br \/>\n  substance which would issue from a retort if I were to put some chalk into it<br \/>\n  with a little moisture and make it red-hot; you would then find that exactly<br \/>\n  the same substance would issue from it as from the candle.<\/P><br \/>\n  <P>But we have a better means of getting this substance, and in greater<br \/>\n  quantity, so as to ascertain what its general characters are. We find this<br \/>\n  substance in very great abundance in a multitude of cases where you would<br \/>\n  least expect it. All limestones contain a great deal of this gas which issues<br \/>\n  from the candle, and which we call carbonic acid. All chalks, all shells, all<br \/>\n  corals, contain a great quantity of this curious air. We find it fixed in<br \/>\n  these stones, for which reason Dr. Black called it &#8220;fixed air&#8221; &#8211; finding it in<br \/>\n  these fixed things like marble and chalk &#8211; he called it fixed air because it<br \/>\n  lost its quality of air, and assumed the condition of a solid body. We can<br \/>\n  easily get this air from marble. Here is a jar containing a little muriatic<br \/>\n  acid, and here is a taper which, if I put it into that jar, will show only the<br \/>\n  presence of common air. There is, you see, pure air down to the bottom; the<br \/>\n  jar is full of it. Here is a substance &#8211; marble <SUP>18<\/SUP>, a very<br \/>\n  beautiful and superior marble &#8211; and if I put these pieces of marble into the<br \/>\n  jar, a great boiling apparently goes on. That, however, is not steam; it is a<br \/>\n  gas that is rising up; and if I now search the jar by a candle, I shall have<br \/>\n  exactly the same effect produced upon the taper as I had from the air which<br \/>\n  issued from the end of the chimney over the burning candle. It is exactly the<br \/>\n  same action, and caused by the very same substance that issued from the<br \/>\n  candle; and in this way we can get carbonic acid in great abundance &#8211; we have<br \/>\n  already nearly filled the jar. We also find that this gas is not merely<br \/>\n  contained in marble. Here is a vessel in which I have put some common<br \/>\n  whitening-chalk which has been washed in water and deprived of its coarser<br \/>\n  particles, and so supplied to the plasterer as whitening &#8211; here is a large jar<br \/>\n  containing this whitening and water; and I have here some strong sulphuric<br \/>\n  acid, which is the acid you might have to use if you were to make these<br \/>\n  experiments (only, in using this acid with limestone, the body that is<br \/>\n  produced is an insoluble substance, whereas the muriatic acid produces a<br \/>\n  soluble substance that does not so much thicken the water). And you will seek<br \/>\n  out a reason why I take this kind of apparatus for the purpose of showing this<br \/>\n  experiment. I do it because you may repeat in a small way what I am about to<br \/>\n  do in a large one. You will have here just the same kind of action; and I am<br \/>\n  evolving in this large jar carbonic acid exactly the same in its nature and<br \/>\n  properties as the gas which we obtained from the combustion of the candle in<br \/>\n  the atmosphere. And, no matter how different the two methods by which we<br \/>\n  prepare this carbonic acid, you will see, when we get to the end of our<br \/>\n  subject, that it is all exactly the same, whether prepared in the one way or<br \/>\n  in the other.<\/P><br \/>\n  <BLOCKQUOTE><br \/>\n    <P>[Footnote 18: Marble is a compound of carbonic acid and lime. The<br \/>\n    muriatic acid, being the stronger of the two, takes the place of the<br \/>\n    carbonic acid, which escapes as a gas, the residue forming muriate of lime<br \/>\n    or chloride of calcium.]<\/P><\/BLOCKQUOTE><br \/>\n  <P>We will now proceed to the next experiment with regard to this gas. What is<br \/>\n  its nature? Here is one of the vessels full, and we will try it as we have<br \/>\n  done so many other gases &#8211; by combustion. You see it is not combustible, nor<br \/>\n  does it support combustion. Neither, as we know, does it dissolve much in<br \/>\n  water, because we collect it over water very easily. Then you know that it has<br \/>\n  an effect, and becomes white in contact with lime-water; and when it does<br \/>\n  become white in that way, it becomes one of the constituents to make carbonate<br \/>\n  of lime or limestone.<\/P><\/p>\n<p>  <P>The next thing I must show you is that it really does dissolve a little in<br \/>\n  water, and therefore that it is unlike oxygen and hydrogen in that respect. I<br \/>\n  have here an apparatus by which we can produce this solution. In the lower<br \/>\n  part of this apparatus is marble and acid, and in the upper part cold water.<br \/>\n  The valves are so arranged that the gas can get from one to the other. I will<br \/>\n  set it in action now, and you can see the gas bubbling up through the water,<br \/>\n  as it has been doing all night long, and by this time we shall find that we<br \/>\n  have this substance dissolved in the water. If I take a glass and draw off<br \/>\n  some of the water, I find that it tastes a little acid to the mouth; it is<br \/>\n  impregnated with carbonic acid; and if I now apply a little lime-water to it,<br \/>\n  that will give us a test of its presence. This water will make the lime water<br \/>\n  turbid and white, which is proof of the presence of carbonic acid.<\/P><br \/>\n  <P>Then it is a very weighty gas; it is heavier than the atmosphere. I have<br \/>\n  put their respective weights at the lower part of this table, along with, for<br \/>\n  comparison, the weights of the other gases we have been examining:<\/P><br \/>\n  <P>&#8212;Table 3]<\/P><br \/>\n  <P>A pint of it weighs 16-1\/3 grains, and a cubic foot weighs 1-9\/10 ounce,<br \/>\n  almost two ounces. You can see by many experiments that this is a heavy gas.<br \/>\n  Suppose I take a glass containing nothing else but air, and from this vessel<br \/>\n  containing the carbonic acid I attempt to pour a little of this gas into that<br \/>\n  glass &#8211; I wonder whether any has gone in or not. I can not tell by the<br \/>\n  appearance, but I can in this way [introducing the taper]. Yes, there it is,<br \/>\n  you see; and if I were to examine it by lime-water, I should find it by that<br \/>\n  test also. I will take this little bucket, and put it down into the well of<br \/>\n  carbonic acid &#8211; indeed, we too often have real wells of carbonic acid &#8211; and<br \/>\n  now, if there is any carbonic acid, I must have got to it by this time, and it<br \/>\n  will be in this bucket, which we will examine with a taper. There it is, you<br \/>\n  see; it is full of carbonic acid.<\/P><br \/>\n  <P>There is another experiment by which I will show you its weight. I have<br \/>\n  here a jar suspended at one end of a balance &#8211; it is now equipoised; but when<br \/>\n  I pour this carbonic acid into the jar on the one side which now contains air,<br \/>\n  you will see it sink down at once because of the carbonic acid that I pour<br \/>\n  into it. And now, if I examine this jar with the lighted taper, I shall find<br \/>\n  that the carbonic acid has fallen into it, and it no longer has any power of<br \/>\n  supporting the combustion. If I blow a soap bubble, which of course will be<br \/>\n  filled with air, and let it fall into this jar of carbonic acid, it will<br \/>\n  float. But I shall first of all take one of these little balloons filled with<br \/>\n  air. I am not quite sure where the carbonic acid is; we will just try the<br \/>\n  depth, and see whereabouts is its level. There, you see, we have this bladder<br \/>\n  floating on the carbonic acid; and if I evolve some more of the carbonic acid,<br \/>\n  the bladder will be lifted up higher. There it goes; the jar is nearly full,<br \/>\n  and now I will see whether I can blow a soap bubble on that and float it in<br \/>\n  the same way. [The lecturer here blew a soap bubble and allowed it to fall<br \/>\n  into the jar of carbonic acid, when it floated in it midway.] It is floating,<br \/>\n  as the balloon floated, by virtue of the greater weight of the carbonic acid<br \/>\n  than of the air. And now, having so far given you the history of the carbonic<br \/>\n  acid, as to its sources in the candle, as to its physical properties and<br \/>\n  weight, when we next meet I shall show you of what it is composed, and where<br \/>\n  it gets its elements from.<\/P><br \/>\n  <P><BR><STRONG><A name=\"Lecture VI\">Lecture VI<\/A>: Carbon Or<br \/>\n  Charcoal &#8211; Coal Gas &#8211; Respiration And Its Analogy To A<br \/>\n  Candle<\/STRONG><\/P><\/p>\n<p>  <P>A Lady who honors me by her presence at these lectures has conferred a<br \/>\n  still farther obligation by sending me these two candles, which are from<br \/>\n  japan, and, I presume, are made of that substance to which I referred in a<br \/>\n  former lecture. You see that they are even far more highly ornamented than the<br \/>\n  French candles, and, I suppose, are candles of luxury, judging from their<br \/>\n  appearance. They have a remarkable peculiarity about them, &#8211; namely, a hollow<br \/>\n  wick, &#8211; that beautiful peculiarity which Argand introduced into the lamp and<br \/>\n  made so valuable. To those who receive such presents from the East, I may just<br \/>\n  say that this and such like materials gradually undergo a change which gives<br \/>\n  them on the surface a dull and dead appearance; but they may easily be<br \/>\n  restored to their original beauty if the surface be rubbed with a clean cloth<br \/>\n  or silk handkerchief, so as to polish the little rugosity or roughness: this<br \/>\n  will restore the beauty of the colors. I have so rubbed one of these candles,<br \/>\n  and you see the difference between it and the other which has not been<br \/>\n  polished, but which may be restored by the same process. Observe, also, that<br \/>\n  these moulded candles from Japan are made more conical than the moulded<br \/>\n  candles in this part of the world.<\/P><br \/>\n  <P>I told you, when we last met, a good deal about carbonic acid. We found by<br \/>\n  the lime-water test that when the vapor from the top of the candle or lamp was<br \/>\n  received into bottles and tested by this solution of lime-water (the<br \/>\n  composition of which I explained to you, and which you can make for<br \/>\n  yourselves), we had that white opacity which was in fact calcareous matter,<br \/>\n  like shells and corals, and many of the rocks and minerals in the earth. But I<br \/>\n  have not yet told you fully and clearly the chemical history of this<br \/>\n  substance, carbonic acid, as we have it from the candle, and I must now resume<br \/>\n  that subject. We have seen the products, and the nature of them, as they issue<br \/>\n  from the candle. We have traced the water to its elements, and now we have to<br \/>\n  see where are the elements of the carbonic acid supplied by the candle. A few<br \/>\n  experiments will show this. You remember that when a candle burns badly it<br \/>\n  produces smoke; but if it is burning well there is no smoke. And you know that<br \/>\n  the brightness of the candle is due to this smoke, which becomes ignited. Here<br \/>\n  is an experiment to prove this: so long as the smoke remains in the flame of<br \/>\n  the candle and becomes ignited, it gives a beautiful light, and never appears<br \/>\n  to us in the form of black particles. I will light some fuel which is<br \/>\n  extravagant in its burning. This will serve our purpose &#8211; a little turpentine<br \/>\n  on a sponge. You see the smoke rising from it, and floating into the air in<br \/>\n  large quantities; and remember now, the carbonic acid that we have from the<br \/>\n  candle is from such smoke as that. To make that evident to you, I will<br \/>\n  introduce this turpentine burning on the sponge into a flask where I have<br \/>\n  plenty of oxygen, the rich part of the atmosphere, and you now see that the<br \/>\n  smoke is all consumed. This is the first part of our experiment; and now, what<br \/>\n  follows? The carbon which you saw flying off from the turpentine flame in the<br \/>\n  air is now entirely burned in this oxygen, and we shall find that it will, by<br \/>\n  this rough and temporary experiment, give us exactly the same conclusion and<br \/>\n  result as we had from the combustion of the candle. The reason why I make the<br \/>\n  experiment in this manner is solely that I may cause the steps of our<br \/>\n  demonstration to be so simple that you can never for a moment lose the train<br \/>\n  of reasoning, if you only pay attention. All the carbon which is burned in<br \/>\n  oxygen, or air, comes out as carbonic acid, while those particles which are<br \/>\n  not so burned show you the second substance in the carbonic acid, &#8211; namely,<br \/>\n  the carbon &#8211; that body which made the flame so bright while there was plenty<br \/>\n  of air, but which was thrown off in excess when there was not oxygen enough to<br \/>\n  burn it.<\/P><br \/>\n  <P>I have also to show you a little more distinctly the history of carbon and<br \/>\n  oxygen in their union to make carbonic acid. You are now better able to<br \/>\n  understand this than before, and I have prepared three or four experiments by<br \/>\n  way of illustration. This jar is filled with oxygen, and here is some carbon<br \/>\n  which has been placed in a crucible for the purpose of being made red-hot. I<br \/>\n  keep my jar dry, and venture to give you a result imperfect in some degree, in<br \/>\n  order that I may make the experiment brighter. I am about to put the oxygen<br \/>\n  and the carbon together. That this is carbon (common charcoal pulverized) you<br \/>\n  will see by the way in which it burns in the air [letting some of the red hot<br \/>\n  charcoal fall out of the crucible]. I am now about to burn it in oxygen gas,<br \/>\n  and look at the difference. It may appear to you at a distance as if it were<br \/>\n  burning with a flame; but it is not so. Every little piece of charcoal is<br \/>\n  burning as a spark, and while it so burns it is producing carbonic acid. I<br \/>\n  specially want these two or three experiments to point out what I shall dwell<br \/>\n  upon more distinctly by-and-by &#8211; that carbon burns in this way, and not as a<br \/>\n  flame.<\/P><br \/>\n  <P>Instead of taking many particles of carbon to burn, I will take a rather<br \/>\n  large piece, which will enable you to see the form and size, and to trace the<br \/>\n  effects very decidedly. Here is the jar of oxygen, and here is the piece of<br \/>\n  charcoal, to which I have fastened a little piece of wood, which I can set<br \/>\n  fire to, and so commence the combustion, which I could not conveniently do<br \/>\n  without. You now see the charcoal burning, but not as a flame (or if there be<br \/>\n  a flame it is the smallest possible one, which I know the cause of, namely,<br \/>\n  the formation of a little carbonic oxide close upon the surface of the<br \/>\n  carbon). It goes on burning, you see, slowly producing carbonic acid by the<br \/>\n  union of this carbon or charcoal (they are equivalent terms) with the oxygen.<br \/>\n  I have here another piece of charcoal, a piece of bark, which has the quality<br \/>\n  of being blown to pieces &#8211; exploding &#8211; as it burns. By the effect of the heat<br \/>\n  we shall reduce the lump of carbon into particles that will fly off; still<br \/>\n  every particle, equally with the whole mass, burns in this peculiar way &#8211; it<br \/>\n  burns as a coal and not like a flame. You observe a multitude of little<br \/>\n  combustions going on, but no flame. I do not know a finer experiment than this<br \/>\n  to show that carbon burns with a park.<\/P><br \/>\n  <P>Here, then, is carbonic acid formed from its elements. It is produced at<br \/>\n  once; and if we examined it by lime-water you will see that we have the same<br \/>\n  substance which I have previously described to you. By putting together 6<br \/>\n  parts of carbon by weight (whether it comes from the flame of a candle or from<br \/>\n  powdered charcoal) and 16 parts of oxygen by weight, we have 22 parts of<br \/>\n  carbonic acid; and, as we saw last time, the 22 parts of carbonic acid<br \/>\n  combined with 28 parts of lime, product common carbonate of lime. If you were<br \/>\n  to examine an oyster-shell and weigh the component parts, you would find that<br \/>\n  every 50 parts would give 6 of carbon and 16 of oxygen combined with 28 of<br \/>\n  lime. However, I do not want to trouble you with these minutiae; it is only<br \/>\n  the general philosophy of the matter that we can now go into. See how finely<br \/>\n  the carbon is dissolving away [pointing to the lump of charcoal burning<br \/>\n  quietly in the jar of oxygen]. You may say that the charcoal is actually<br \/>\n  dissolving in the air round about; and if that were perfectly pure charcoal,<br \/>\n  which we can easily prepare, there would be no residue whatever. When we have<br \/>\n  a perfectly cleansed and purified piece of carbon, there is no ash left. The<br \/>\n  carbon burns as a solid dense body, that heat alone can not change as to its<br \/>\n  solidity, and yet it passes away into vapor that never condenses into solid or<br \/>\n  liquid under ordinary circumstances; and what is more curious still is the<br \/>\n  fact that the oxygen does not change in its bulk by the solution of the carbon<br \/>\n  in it. Just as the bulk is at first, so it is at last, only it has become<br \/>\n  carbonic acid.<\/P><br \/>\n  <P>There is another experiment which I must give you before you are fully<br \/>\n  acquainted with the general nature of carbonic acid. Being a compound body,<br \/>\n  consisting of carbon and oxygen, carbonic acid is a body that we ought to be<br \/>\n  able to take asunder. And so we can. As we did with water, so we can with<br \/>\n  carbonic acid &#8211; take the two parts asunder. The simplest and quickest way is<br \/>\n  to act upon the carbonic acid by a substance that can attract the oxygen from<br \/>\n  it, and leave the carbon behind. You recollect that I took potassium and put<br \/>\n  it upon water or ice, and you saw that it could take the oxygen from the<br \/>\n  hydrogen. Now, suppose we do something of the same kind here with this<br \/>\n  carbonic acid. You know carbonic acid to be a heavy gas. I will not test it<br \/>\n  with lime-water, as that will interfere with our subsequent experiments, but I<br \/>\n  think the heaviness of the gas and the power of extinguishing flame will be<br \/>\n  sufficient for our purpose. I introduce a flame into the gas, and you will see<br \/>\n  whether it will be put out. You see the light is extinguished. Indeed, the gas<br \/>\n  may, perhaps, put out phosphorus, which you know has a pretty strong<br \/>\n  combustion. Here is a piece of phosphorus heated to a high degree. I introduce<br \/>\n  it into gas, and you observe the light is put out, but it will take fire again<br \/>\n  in the air, because there it re-enters into combustion. Now let me take a<br \/>\n  piece of potassium, a substance which even at common temperatures can act upon<br \/>\n  carbonic acid, though not sufficiently for our present purpose, because it<br \/>\n  soon gets covered with a protecting coat; but if we warm it up to the burning<br \/>\n  point in air, as we have a fair right to do, and as we have done with<br \/>\n  phosphorus, you will see that it can burn in carbonic acid; and if it burns,<br \/>\n  it will burn by taking oxygen, so that you will see what is left behind. I am<br \/>\n  going, then, to burn this potassium in the carbonic acid, as a proof of the<br \/>\n  existence of oxygen in the carbonic acid. [In the preliminary process of<br \/>\n  heating the potassium exploded.] Sometimes we get an awkward piece of<br \/>\n  potassium that explodes, or something like it, when it burns. I will take<br \/>\n  another piece, and now that it is heated I introduce it into the jar, and you<br \/>\n  perceive that it burns in the carbonic acid &#8211; not so well as in the air,<br \/>\n  because the carbonic acid contains the oxygen combined; but it does burn, and<br \/>\n  takes away the oxygen. If I now put this potassium into water, I find that<br \/>\n  besides the potash formed (which you need not trouble about) there is a<br \/>\n  quantity of carbon produced. I have here made the experiment in a very rough<br \/>\n  way, but I assure you that if I were to make it carefully, devoting a day to<br \/>\n  it instead of five minutes, we should get all the proper amount of charcoal<br \/>\n  left in the spoon, or in the place where the potassium was burned, so that<br \/>\n  there could be no doubt as to the result. Here, then, is the carbon obtained<br \/>\n  from the carbonic acid, as a common black substance; so that you have the<br \/>\n  entire proof of the nature of carbonic acid as consisting of carbon and<br \/>\n  oxygen. And now I may tell you, that whenever carbon burns under common<br \/>\n  circumstances it produces carbonic acid.<\/P><\/p>\n<p>  <P>Suppose I take this piece of wood, and put it into a bottle with lime<br \/>\n  water. I might shake that lime-water up with wood and the atmosphere as long<br \/>\n  as I pleased, it would still remain clear as you see it; but suppose I burn<br \/>\n  the piece of wood in the air of that bottle. You, of course, know I get water.<br \/>\n  Do I get carbonic acid? [The experiment was performed.] There it is, you see<br \/>\n  that is to say, the carbonate of lime, which results from carbonic acid, and<br \/>\n  that carbonic acid must be formed from the carbon which comes from the wood,<br \/>\n  from the candle, or any other thing. Indeed, you have yourselves frequently<br \/>\n  tried a very pretty experiment, by which you may see the carbon in wood. If<br \/>\n  you take a piece of wood, and partly burn it, and then blow it out, you have<br \/>\n  carbon left. There are things that do not show carbon in this way. A candle<br \/>\n  does not so show it, but it contains carbon. Here also is a jar of coal gas,<br \/>\n  which produces carbonic acid abundantly; you do not see the carbon, but we can<br \/>\n  soon show it to you. I will light it, and as long as there is any gas in the<br \/>\n  cylinder it will go on burning. You see no carbon, but you see a flame, and<br \/>\n  because that is bright it will lead you to guess that there is carbon in the<br \/>\n  flame. But I will show it to you by another process. I have some so the same<br \/>\n  gas in another vessel, mixed with a body that will burn the hydrogen of the<br \/>\n  gas, but will not burn the carbon. I will light them with a burning taper, and<br \/>\n  you perceive the hydrogen is consumed, but not the carbon, which is left<br \/>\n  behind as a dense black smoke. I hope that by these three or four experiments<br \/>\n  you will learn to see when carbon is present, and understand what are the<br \/>\n  products of combustion when gas or other bodies are thoroughly burned in the<br \/>\n  air.<\/P><br \/>\n  <P>Before we leave the subject of carbon, let us make a few experiments and<br \/>\n  remarks upon its wonderful condition as respects ordinary combustion. I have<br \/>\n  shown you that the carbon, in burning burns only as a solid body, and yet you<br \/>\n  perceive that, after it is burned, it ceases to be a solid. There are very few<br \/>\n  fuels that act like this. It is, in fact, only that great source of fuel, the<br \/>\n  carbonaceous series, the coals, charcoals, and woods, that can do it. I do not<br \/>\n  know that there is any other elementary substance besides carbon that burns<br \/>\n  with these conditions; and if it had not been so, what would happen to us?<br \/>\n  Suppose all fuel had been like iron, which, when it burns, burns into a solid<br \/>\n  substance. We could not then have such a combustion as you have in this<br \/>\n  fireplace. Here also is another kind of fuel which burns very-well as, if not<br \/>\n  better, than carbon &#8211; so well, indeed, as to take fire of itself when it is in<br \/>\n  the air, as you see [breaking a tube full of lead pyrophorus]. This substance<br \/>\n  is lead, and you see how wonderfully combustible it is. It is very much<br \/>\n  divided, and is like a heap of coals in the fireplace; the air can get to its<br \/>\n  surface and inside, and so it burns. But why does it burn in that way now,<br \/>\n  when it is lying in a mass? [emptying the contents of the tube in a heap on to<br \/>\n  a plate of iron.] Simply because the air can not get to it. Though it can<br \/>\n  produce a great heat, the great heat which we want in our furnaces and under<br \/>\n  our boilers, still that which is produced can not get away from the portion<br \/>\n  which remains unburned underneath, and that portion, therefore, is prevented<br \/>\n  from coming in contact with the atmosphere, and can not be consumed. How<br \/>\n  different is that from carbon! Carbon burns just in the same way as this lead<br \/>\n  does, and so gives an intense fire in the furnace, or wherever you choose to<br \/>\n  burn it; but then the body produced by its combustion passes away, and the<br \/>\n  remaining carbon is left clear. I showed you how carbon went on dissolving in<br \/>\n  the oxygen, leaving no ash, whereas here [pointing to the heap of pyrophorus]<br \/>\n  we have actually more ash than fuel, for it is heavier by the amount of the<br \/>\n  oxygen which has united with it. Thus you see the difference between carbon<br \/>\n  and lead or iron &#8211; if we choose iron, which gives so wonderful a result in our<br \/>\n  applications of this fuel, either as light or heat. If, when the carbon burnt,<br \/>\n  the product went off as a solid body, you would have had the room filled with<br \/>\n  an opaque substance, as in the case of the phosphorus; but when carbon burns,<br \/>\n  every thing passes up into the atmosphere. It is in a fixed, almost<br \/>\n  unchangeable condition before the combustion; but afterward it is in the form<br \/>\n  of gas, which it is very difficult (though we have succeeded) to produce in a<br \/>\n  solid or liquid state.<\/P><br \/>\n  <P>Now I must take you to a very interesting part of our subject &#8211; to the<br \/>\n  relation between the combustion of a candle and that living kind of combustion<br \/>\n  which goes on within us. In every one of us there is a living process of<br \/>\n  combustion going on very similar to that of a candle, and I must try to make<br \/>\n  that plain to you. For it is not merely true in a poetical sense &#8211; the<br \/>\n  relation of the life of man to a taper; and if you will follow, I think I can<br \/>\n  make this clear. In order to make the relation very plain, I have devised a<br \/>\n  little apparatus which we can soon build up before you. Here is a board, and a<br \/>\n  groove cut in it, and I can close the groove at the top part by a little<br \/>\n  cover; I can then continue the groove as a channel by a glass tube at each<br \/>\n  end, there being a free passage through the whole. Suppose I take a taper or<br \/>\n  candle (we can now be liberal in our use of the word &#8220;candle,&#8221; since we<br \/>\n  understand what it means), and place it in one of the tubes; it will go on,<br \/>\n  you see, burning very well. You observe that the air which feeds the flame<br \/>\n  passes down the tube at one end, then goes along the horizontal tube, and<br \/>\n  ascends the tube at the other end in which the taper is placed. If I stop the<br \/>\n  aperture through which the air enters, I stop combustion, as you perceive. I<br \/>\n  stop the supply of air, and consequently the candle goes out. But now what<br \/>\n  will you think of this fact? In a former experiment I showed you the air going<br \/>\n  from one burning candle to a second candle. If I took the air proceeding from<br \/>\n  another candle, and sent it down by a complicated arrangement into this tube,<br \/>\n  I should put this burning candle out. But what will you say when I tell you<br \/>\n  that my breath will put out the candle? I do not mean by blowing at all, but<br \/>\n  simply that the nature of my breath is such that a candle can not burn in it.<br \/>\n  I will now hold my mouth over the aperture, and without blowing the flame in<br \/>\n  any way, let no air enter the tube but what comes from my mouth. You see the<br \/>\n  result. I did not blow the candle out. I merely let the air which I expired<br \/>\n  pass into the aperture, and the result was that the light went out for want of<br \/>\n  oxygen, and for no other reason. Something or other &#8211; namely, my lungs &#8211; had<br \/>\n  taken away the oxygen from the air and there was no more to supply combustion<br \/>\n  of the candle. It is, I think, very pretty to see the time it takes before the<br \/>\n  bad air which I throw into this part of the apparatus has reached the candle.<br \/>\n  The candle at first goes on burning, but so soon as the air has had time to<br \/>\n  reach it, it goes out. And now I will show you another experiment, because<br \/>\n  this is an important part of our philosophy. Here is a jar which contains<br \/>\n  fresh air, as you can seen by the circumstance of a candle or gas light<br \/>\n  burning it. I make it close for a little time, and by means of a pipe I get my<br \/>\n  mouth over it so that I can inhale the air. By putting it over water, in the<br \/>\n  way that you see, I am able to draw up this air (supposing the cork to be<br \/>\n  quite tight), take it into my lungs, and throw it back into the jar: we can<br \/>\n  then examine it, and see the result. You observe, I first take up the air, and<br \/>\n  then throw it back, as is evident from the ascent and descent of the water;<br \/>\n  and now, by putting a taper into the air, you will see the state in which it<br \/>\n  is, by the light being extinguished. Even one inspiration, you see, has<br \/>\n  completely spoiled this air, so that it is no use my trying to breathe it a<br \/>\n  second time. Now you understand the ground of the impropriety of many of the<br \/>\n  arrangements among the houses of the poorer classes, by which the air is<br \/>\n  breathed over and over again for the want of a supply, by means of proper<br \/>\n  ventilation, sufficient to produce a good result. You see how bad the air<br \/>\n  becomes by a single breathing, so that you can easily understand how essential<br \/>\n  fresh air is to us.<\/P><br \/>\n  <P>To pursue this a little farther, let us see what will happen with lime<br \/>\n  water. Here is a globe which contains a little lime-water, and it is so<br \/>\n  arranged as regards the pipes, as to give access to the air within, so that we<br \/>\n  can ascertain the effect of respired or unrespired air upon it. Of course I<br \/>\n  can either draw in air (through A), and so make the air that feeds my lungs go<br \/>\n  through the lime-water, or I can force the air out of my lungs through the<br \/>\n  tube (B), which goes to the bottom, and so show its effect upon the lime<br \/>\n  water. You will observe that however long I draw the external air into the<br \/>\n  lime-water and then through it to my lungs, I shall produce no effect upon the<br \/>\n  water &#8211; it will not make the lime-water turbid; but if I throw the air from my<br \/>\n  lungs through the lime-water several times is succession, you see how white<br \/>\n  the milky the water is getting showing the effect which expired air has had<br \/>\n  upon it; and now you begin to know that the atmosphere which we have spoiled<br \/>\n  by respiration is spoiled by carbonic acid, for you see it here in contact<br \/>\n  with the lime-water.<\/P><br \/>\n  <P>I have here two bottles, one containing lime-water and the other common<br \/>\n  water, and tubes which pass into the bottles and connect them. The apparatus<br \/>\n  is very rough, but it is useful notwithstanding. If I take these two bottles,<br \/>\n  inhaling here and exhaling there, the arrangement of the tubes will prevent<br \/>\n  the air going backward. The air coming in will go to my mouth and lungs, and<br \/>\n  in going out will pass through the lime-water, so that I can go on breathing,<br \/>\n  and making an experiment very refined in its nature and very good in its<br \/>\n  results. You will observe that the good air has done nothing to the<br \/>\n  lime-water; in the other case, nothing has come to the lime-water but my<br \/>\n  respiration, and you see the difference in the two cases.<\/P><br \/>\n  <P>Let us now go a little farther. What is all this process going on within us<br \/>\n  which we can not do without, either day or night, which is provided for by the<br \/>\n  Author of all things that He has arranged that it shall be independent of all<br \/>\n  will? If we restrain our respiration, as we can to a certain extent, we should<br \/>\n  destroy ourselves. When we are asleep the organs of respiration and the parts<br \/>\n  that are associated with them still go on with their action, so necessary is<br \/>\n  this process of respiration to us, this contact of the air with the lungs. I<br \/>\n  must tell you, in the briefest possible manner, what this process is. We<br \/>\n  consume food; the food goes through that strange set of vessels and organs<br \/>\n  within us, and is brought into various parts of the system, into the digestive<br \/>\n  parts especially; and alternately the portion which is so changed is carried<br \/>\n  through our lungs by one set of vessels, while the air that we inhale and<br \/>\n  exhale is drawn into and thrown out of the lungs by another set of vessels, so<br \/>\n  that the air and the food come close together, separated only by an<br \/>\n  exceedingly thin surface; the air can thus act upon the blood by this process,<br \/>\n  producing precisely the same results in kind as we have seen in the case of<br \/>\n  the candle. The candle combines with parts of the air, forming carbonic acid,<br \/>\n  and evolves heat; so in the lungs there is this curious, wonderful change<br \/>\n  taking place. The air entering, combines with the carbon (not carbon in a free<br \/>\n  state, but, as in this case, placed ready for action at the moment), and makes<br \/>\n  carbonic acid and is so thrown out into the atmosphere, and thus this singular<br \/>\n  result takes place; we may thus look upon the food as fuel. Let me take that<br \/>\n  piece of sugar, which will serve my purpose. It is a compound of carbon,<br \/>\n  hydrogen, and oxygen, similar to a candle, as containing the same elements,<br \/>\n  though not in the same proportion, the proportions being as shown in this<br \/>\n  table:<\/P><\/p>\n<p>  <P>&#8212;Table 4]<\/P><br \/>\n  <P>This is, indeed, a very curious thing, which you can well remember, for the<br \/>\n  oxygen and hydrogen are in exactly the proportions which form water, so that<br \/>\n  sugar may be said to be compounded of 72 parts of carbon and 99 parts of<br \/>\n  water; and it is the carbon in the sugar that combines with the oxygen carried<br \/>\n  in by the air in the process of respiration &#8211; so making us like candles &#8211;<br \/>\n  producing these actions, warmth, and far more wonderful results besides, for<br \/>\n  the sustenance of the system, by a most beautiful and simple process. To make<br \/>\n  this still more striking, I will take a little sugar; or, to hasten the<br \/>\n  experiment, I will use some sirup, which contains about three-fourths of sugar<br \/>\n  and a little water. If I put a little oil of vitriol on it, it takes away the<br \/>\n  water, and leaves the carbon in a black mass. [The lecturer mixed the two<br \/>\n  together.] You see how the carbon is coming out, and before long we shall have<br \/>\n  a solid mass of charcoal, all of which has come out of sugar. Sugar, as you<br \/>\n  know, is food, and here we have absolutely a solid lump of carbon where you<br \/>\n  would not have expected it. And if I make arrangements so as to oxidize the<br \/>\n  carbon of sugar we shall have a much more striking result. Here is sugar, and<br \/>\n  I have here an oxidizer &#8211; a quicker one than the atmosphere; and so we shall<br \/>\n  oxidize this fuel by a process different from respiration in its form, though<br \/>\n  not different in its kind. It is the combustion of the carbon by the contact<br \/>\n  of oxygen which the body has supplied to it. If I set this into action at<br \/>\n  once, you will see combustion produced. Just what occurs in my lungs &#8211; taking<br \/>\n  in oxygen from another source, namely, the atmosphere &#8211; takes place here by a<br \/>\n  more rapid process.<\/P><br \/>\n  <P>You will be astonished when I tell you what this curious play of carbon<br \/>\n  amounts to. A candle will burn some four, five, six, or seven hours. What,<br \/>\n  then, must be the daily amount of carbon going up into the air in the way of<br \/>\n  carbonic acid! What a quantity of carbon must go from each of us in<br \/>\n  respiration! What a wonderful change of carbon must take place under these<br \/>\n  circumstances of combustion or respiration! A man in twenty-four hours<br \/>\n  converts as much as seven ounces of carbon into carbonic acid; a milch cow<br \/>\n  will convert seventy ounces, and a horse seventy-nine ounces, solely by the<br \/>\n  act of respiration. That is, the horse in twenty-four hours burns seventy nine<br \/>\n  ounces of charcoal, or carbon, in his organs of respiration to supply his<br \/>\n  natural warmth in that time. All the warm-blooded animals get their warmth in<br \/>\n  this way, by the conversion of carbon, not in a free state, but in a state of<br \/>\n  combination. And what an extraordinary notion this gives us of the alterations<br \/>\n  going on in our atmosphere. As much as 5,000,000 pounds, or 548 tons, of<br \/>\n  carbonic acid is formed by respiration in London alone in twenty four hours.<br \/>\n  And where does all this go? Up into the air. If the carbon had been like the<br \/>\n  lead which I showed you, or the iron which, in burning, produces a solid<br \/>\n  substance, what would happen? Combustion could not go on. As charcoal burns it<br \/>\n  becomes a vapor and passes off into the atmosphere, which is the great<br \/>\n  vehicle, the great carrier for conveying it away to other places. Then what<br \/>\n  becomes of it? Wonderful is it to find that the change produced by<br \/>\n  respiration, which seems so injurious to us (for we can not breathe air twice<br \/>\n  over), is the very life and support of plants and vegetables that grow upon<br \/>\n  the surface of the earth. It is the same also under the surface, in the great<br \/>\n  bodies of water; for fishes and other animals respire upon the same principle,<br \/>\n  though not exactly by contact with the open air.<\/P><br \/>\n  <P>Such fish as I have here [pointing to a globe of goldfish] respire by the<br \/>\n  oxygen which is dissolved from the air by the water, and form carbonic acid,<br \/>\n  and they all move about to produce the one great work of making the animal and<br \/>\n  vegetable kingdoms subservient to each other. And all the plants growing upon<br \/>\n  the surface of the earth, like that which I have brought here to serve as an<br \/>\n  illustration, absorb carbon; these leaves are taking up their carbon from the<br \/>\n  atmosphere to which we have given it in the form of carbonic acid, and they<br \/>\n  are growing and prospering. Give them a pure air like ours, and they could not<br \/>\n  live in it; give them carbon with other matters, and they live and rejoice.<br \/>\n  This piece of wood gets all its carbon, as the trees and plants get theirs,<br \/>\n  from the atmosphere, which, as we have seen, carries away what is bad for us<br \/>\n  and at the same time good for them &#8211; what is disease to the one being health<br \/>\n  to the other. So are we made dependent not merely upon our fellow-creatures,<br \/>\n  but upon our fellow-existers, all Nature being tied together by the laws that<br \/>\n  make one part conduce to the good of another.<\/P><br \/>\n  <P>There is another little point which I must mention before we draw to a<br \/>\n  close &#8211; a point which concerns the whole of beauty of the taper by making your<br \/>\n  deeds honorable and effectual in the discharge of your duty to your<br \/>\n  fellow-men.<\/P><br \/>\n  <BLOCKQUOTE><\/p>\n<p>    <P>[Footnote 19: Lead pyrophorus is made by heating dry tartrate of lead in<br \/>\n    a glass tube (closed at one end, and drawn out to a fine point at the other)<br \/>\n    until no more vapors are evolved. The open end of the tube is then to be<br \/>\n    sealed before the blowpipe. When the tube is broken and the contents shaken<br \/>\n    out into the air, they burn with a red flash.]<\/P><\/BLOCKQUOTE><\/BLOCKQUOTE><br \/>\n<HR><br \/>\n<BLOCKQUOTE><br \/>\n  <P><STRONG>Source:<\/STRONG><\/P><br \/>\n  <P><EM>Scientific papers: physics, chemistry, astronomy, geology, with<br \/>\n  introductions, notes and illustrations<\/EM>. New York, P. F. Collier &amp; son<br \/>\n  [c1910], Harvard classics ; no.XXX.<\/P><\/BLOCKQUOTE><br \/>\n<HR><br \/>\n<BLOCKQUOTE><br \/>\n  <P>This text is in the public domain<\/p>\n<p><P><\/BLOCKQUOTE><\/p>\n<p>\n","protected":false},"excerpt":{"rendered":"<p>Modern History Sourcebook: Michael Faraday (1791-1867): The Chemical History of A Candle, 1860 Introductory Note Michael Faraday was the son of a blacksmith, and was born at Newington Butts, near London, September 22, 1791. He began life as an errand &hellip;<\/p>\n<p class=\"read-more\"> <a class=\"more-link\" href=\"http:\/\/www.radio-active.net.au\/web3\/Personal\/History\/Candle\"> <span class=\"screen-reader-text\">Chemical History of a Candle<\/span> Read More &raquo;<\/a><\/p>\n","protected":false},"author":3,"featured_media":0,"parent":271,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"jetpack_post_was_ever_published":false,"footnotes":""},"jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/P5cfmK-4p","_links":{"self":[{"href":"http:\/\/www.radio-active.net.au\/web3\/wp-json\/wp\/v2\/pages\/273"}],"collection":[{"href":"http:\/\/www.radio-active.net.au\/web3\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"http:\/\/www.radio-active.net.au\/web3\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"http:\/\/www.radio-active.net.au\/web3\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"http:\/\/www.radio-active.net.au\/web3\/wp-json\/wp\/v2\/comments?post=273"}],"version-history":[{"count":1,"href":"http:\/\/www.radio-active.net.au\/web3\/wp-json\/wp\/v2\/pages\/273\/revisions"}],"predecessor-version":[{"id":274,"href":"http:\/\/www.radio-active.net.au\/web3\/wp-json\/wp\/v2\/pages\/273\/revisions\/274"}],"up":[{"embeddable":true,"href":"http:\/\/www.radio-active.net.au\/web3\/wp-json\/wp\/v2\/pages\/271"}],"wp:attachment":[{"href":"http:\/\/www.radio-active.net.au\/web3\/wp-json\/wp\/v2\/media?parent=273"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}